Nanochannel functionalization using POFs: Progress and prospects

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science Pub Date : 2025-04-28 DOI:10.1016/j.cis.2025.103533

Xuan Kang , Mingyi Yu , Yuan Xu , Zhong Cao , Sebastien Balme , Tianji Ma

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Abstract

Biomimetic nanochannels, inspired by natural ion channels found in living organisms, are synthetic systems designed to replicate the highly selective and efficient ion/molecule transport processes essential for various biological functions. These artificial channels mimic the structural and functional properties of their biological counterparts, offering precise control over ion and molecular transport. Porous organic framework materials (POFs), including metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), have emerged as promising materials for functionalizing nanochannels due to their unique structures and exceptional properties. This functionalization strategy not only enhances the performance of synthetic nanochannels but also broadens their application potential across various fields. This review comprehensively examines the recent progress in the preparation and application of POFs stereoscopic-functionalized solid nanochannels. Special emphasis is placed on their practical applications, including proton conduction, ion-selective membranes, photo-responsive materials, sensing and detection, chiral separation, and catalysis. Finally, the future development prospects and challenges in this research area are discussed, highlighting opportunities for advancing the design and application of biomimetic nanochannels.

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利用POFs实现纳米通道功能化：进展与展望

仿生纳米通道的灵感来自于生物体中的天然离子通道，是一种合成系统，旨在复制各种生物功能所必需的高选择性和高效的离子/分子运输过程。这些人工通道模仿其生物对应物的结构和功能特性，提供对离子和分子运输的精确控制。多孔有机框架材料（POFs），包括金属有机框架（MOFs）和共价有机框架（COFs），由于其独特的结构和优异的性能，已成为功能化纳米通道的有前途的材料。这种功能化策略不仅提高了合成纳米通道的性能，而且拓宽了其在各个领域的应用潜力。本文综述了近年来POFs立体功能化固体纳米通道的制备及应用研究进展。特别强调了它们的实际应用，包括质子传导、离子选择膜、光响应材料、传感和检测、手性分离和催化。最后，讨论了仿生纳米通道的未来发展前景和面临的挑战，强调了推进仿生纳米通道设计和应用的机遇。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Advances in Colloid and Interface Science 化学-物理化学

CiteScore

28.50

自引率

2.60%

发文量

175

审稿时长

31 days

期刊介绍： "Advances in Colloid and Interface Science" is an international journal that focuses on experimental and theoretical developments in interfacial and colloidal phenomena. The journal covers a wide range of disciplines including biology, chemistry, physics, and technology. The journal accepts review articles on any topic within the scope of colloid and interface science. These articles should provide an in-depth analysis of the subject matter, offering a critical review of the current state of the field. The author's informed opinion on the topic should also be included. The manuscript should compare and contrast ideas found in the reviewed literature and address the limitations of these ideas. Typically, the articles published in this journal are written by recognized experts in the field.