UV-curable hydrophobic wood coatings based on sol–gel derived organic–inorganic hybrid systems

IF 2.3 4区 材料科学 Q2 CHEMISTRY, APPLIED
Tahereh Hayeri, Vijay Mannari
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引用次数: 0

Abstract

Wood, valued for its low weight-to-strength ratio, eco-friendly nature, widespread availability, and excellent mechanical properties, plays a crucial role in various applications. Due to its biodegradability and ease of processing, it is a universal building product used in outdoor applications and interior decoration. Our pioneering work focuses on the development of a series of UV-curable organic–inorganic hybrid (OIH) coatings by leveraging sol–gel reactions of organosilane precursors under ambient moisture. The organo-siloxane network formed is to the wood substrate and offers outstanding barrier properties. This hybrid network can be manipulated on micro- or nano-scales by varying the organic–inorganic ratio. The hydrophobic characteristics of the OIH system significantly reduce the interaction between the wood substrate and ambient moisture, enhancing overall durability, abrasion resistance, chemical and stain resistance, and surface cleanability. This innovative approach also eliminates numerous additives and nanoparticles commonly used in conventional wood coatings, thus promoting sustainability. The systems’ versatility is evident in their ability to undergo both ambient curing and UV techniques, making them suitable for a wide range of applications in architectural and industrial coatings, for both indoor and outdoor applications.

基于溶胶-凝胶衍生有机-无机杂化体系的紫外光固化疏水性木器涂料
木材因其重量强度比低、环保、广泛可用和优异的机械性能而受到重视,在各种应用中起着至关重要的作用。由于其可生物降解性和易于加工,它是一种通用的建筑产品,用于室外应用和室内装饰。我们的开创性工作重点是利用有机硅烷前驱体在环境湿度下的溶胶-凝胶反应,开发一系列可紫外光固化的有机-无机杂化(OIH)涂料。形成的有机硅氧烷网络对木材基材具有良好的阻隔性能。通过改变有机-无机比例,可以在微观或纳米尺度上操纵这种混合网络。OIH系统的疏水特性显著减少了木材基材与环境水分之间的相互作用,提高了整体耐久性、耐磨性、耐化学性和耐污性以及表面清洁性。这种创新的方法还消除了传统木器涂料中常用的许多添加剂和纳米颗粒,从而促进了可持续性。该系统的多功能性是显而易见的,因为它们能够经受环境固化和紫外线技术,使它们适用于室内和室外应用的建筑和工业涂料的广泛应用。
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来源期刊
Journal of Coatings Technology and Research
Journal of Coatings Technology and Research 工程技术-材料科学:膜
CiteScore
4.30
自引率
8.70%
发文量
130
审稿时长
2.5 months
期刊介绍: Journal of Coatings Technology and Research (JCTR) is a forum for the exchange of research, experience, knowledge and ideas among those with a professional interest in the science, technology and manufacture of functional, protective and decorative coatings including paints, inks and related coatings and their raw materials, and similar topics.
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