Phenalenyl-based copper complex catalyzed direct biarylation of furan†

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-05-01 DOI:10.1039/D5DT00299K

Krishnendu Paramanik, Nilaj Bandopadhyay, Gayetri Sarkar, Sourav Ghosh, Subhra Jyoti Panda, Chandra Shekhar Purohit, Prasanta Ghosh, Bhaskar Biswas and Hari Sankar Das

引用次数: 0

Abstract

In this work, a newly designed phenalenyl (PLY)-based copper-bipyridine (BPY) heteroleptic system of the form [(BPY)Cu^II(PLY)Cl] has been introduced as a cheap and effective catalytic system for the biarylation of furan using aryldiazonium salts. The crucial function of each unit of [(BPY)Cu^II(PLY)Cl] in this catalytic reaction was determined through a combination of structural, electrochemical, spectroscopic, theoretical, and mechanistic studies.

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苯基铜配合物催化呋喃†的直接双芳基化反应

本文介绍了一种新设计的[(BPY)CuII(PLY)Cl]形式的以苯乙烯基（PLY）为基础的铜-联吡啶（BPY）杂电体系，作为一种廉价而有效的催化体系，用于芳基重氮盐催化呋喃的双芳基化。通过结构、电化学、光谱、理论和机理研究，确定了[(BPY)CuII(PLY)Cl]在催化反应中的每个单元的关键功能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.