{"title":"Revealing the True Thermoelectric Properties of SnTe through Removing SnO2 Contamination","authors":"Yicheng Wang, Rongcheng Li, Bowen Jin, Chenghao Xie, Xinfeng Tang, Gangjian Tan","doi":"10.1007/s40195-025-01838-w","DOIUrl":null,"url":null,"abstract":"<div><p>Previous studies on SnTe have indicated that its low <i>ZT</i> value is associated with a high carrier concentration of up to 10<sup>20</sup>–10<sup>21</sup> cm<sup>−3</sup> and an excessively high lattice thermal conductivity. However, the high carrier concentration and lattice thermal conductivity observed in SnTe are not solely attributable to the presence of numerous intrinsic tin vacancies and a simple crystal structure. Additionally, the oxides formed through the oxidation of Sn and SnTe exert a partial influence on these properties. In this study, by pretreating the raw Sn material and isolating it from oxygen during preparation, we achieve a significant improvement in the thermoelectric performance of binary SnTe at high temperatures, with a peak <i>ZT</i> of approximately 0.83 at 800 K. This approach effectively reduces the content of SnO<sub>2</sub> in the matrix, enhancing the electrical and thermal transport properties of the samples. Specifically, the high-thermal conductivity of SnO<sub>2</sub> facilitates the formation of channels at grain boundaries that are more conducive to heat transfer, while its poor electrical conductivity and Seebeck coefficient diminish the intrinsic electrical transport behavior of SnTe. The removal of SnO<sub>2</sub> reflects the true thermoelectric performance of SnTe, making the samples prepared by this method stand out compared to other reported binary SnTe materials.</p></div>","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 5","pages":"754 - 762"},"PeriodicalIF":2.9000,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Metallurgica Sinica-English Letters","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1007/s40195-025-01838-w","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
Abstract
Previous studies on SnTe have indicated that its low ZT value is associated with a high carrier concentration of up to 1020–1021 cm−3 and an excessively high lattice thermal conductivity. However, the high carrier concentration and lattice thermal conductivity observed in SnTe are not solely attributable to the presence of numerous intrinsic tin vacancies and a simple crystal structure. Additionally, the oxides formed through the oxidation of Sn and SnTe exert a partial influence on these properties. In this study, by pretreating the raw Sn material and isolating it from oxygen during preparation, we achieve a significant improvement in the thermoelectric performance of binary SnTe at high temperatures, with a peak ZT of approximately 0.83 at 800 K. This approach effectively reduces the content of SnO2 in the matrix, enhancing the electrical and thermal transport properties of the samples. Specifically, the high-thermal conductivity of SnO2 facilitates the formation of channels at grain boundaries that are more conducive to heat transfer, while its poor electrical conductivity and Seebeck coefficient diminish the intrinsic electrical transport behavior of SnTe. The removal of SnO2 reflects the true thermoelectric performance of SnTe, making the samples prepared by this method stand out compared to other reported binary SnTe materials.
期刊介绍:
This international journal presents compact reports of significant, original and timely research reflecting progress in metallurgy, materials science and engineering, including materials physics, physical metallurgy, and process metallurgy.