Revealing the True Thermoelectric Properties of SnTe through Removing SnO2 Contamination

IF 2.9 2区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING
Yicheng Wang, Rongcheng Li, Bowen Jin, Chenghao Xie, Xinfeng Tang, Gangjian Tan
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引用次数: 0

Abstract

Previous studies on SnTe have indicated that its low ZT value is associated with a high carrier concentration of up to 1020–1021 cm−3 and an excessively high lattice thermal conductivity. However, the high carrier concentration and lattice thermal conductivity observed in SnTe are not solely attributable to the presence of numerous intrinsic tin vacancies and a simple crystal structure. Additionally, the oxides formed through the oxidation of Sn and SnTe exert a partial influence on these properties. In this study, by pretreating the raw Sn material and isolating it from oxygen during preparation, we achieve a significant improvement in the thermoelectric performance of binary SnTe at high temperatures, with a peak ZT of approximately 0.83 at 800 K. This approach effectively reduces the content of SnO2 in the matrix, enhancing the electrical and thermal transport properties of the samples. Specifically, the high-thermal conductivity of SnO2 facilitates the formation of channels at grain boundaries that are more conducive to heat transfer, while its poor electrical conductivity and Seebeck coefficient diminish the intrinsic electrical transport behavior of SnTe. The removal of SnO2 reflects the true thermoelectric performance of SnTe, making the samples prepared by this method stand out compared to other reported binary SnTe materials.

通过去除SnO2污染揭示SnTe的真实热电性能
先前对SnTe的研究表明,其低ZT值与高达1020-1021 cm−3的高载流子浓度和过高的晶格热导率有关。然而,在SnTe中观察到的高载流子浓度和晶格热导率并不仅仅是由于存在大量的固有锡空位和简单的晶体结构。此外,Sn和SnTe氧化形成的氧化物对这些性能也有部分影响。在本研究中,通过对Sn原料进行预处理,并在制备过程中将其与氧分离,我们实现了二元SnTe在高温下热电性能的显著改善,在800 K时ZT峰值约为0.83。该方法有效降低了基体中SnO2的含量,提高了样品的电输运和热输运性能。具体来说,SnO2的高导热性有利于晶界处形成更有利于传热的通道,而其较差的电导率和塞贝克系数则削弱了SnTe的本禀电输运行为。SnO2的去除反映了SnTe的真实热电性能,使该方法制备的样品与其他二元SnTe材料相比脱颖而出。
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来源期刊
Acta Metallurgica Sinica-English Letters
Acta Metallurgica Sinica-English Letters METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
6.60
自引率
14.30%
发文量
122
审稿时长
2 months
期刊介绍: This international journal presents compact reports of significant, original and timely research reflecting progress in metallurgy, materials science and engineering, including materials physics, physical metallurgy, and process metallurgy.
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