Controls on Dissolved Cu Concentrations and Isotopes in the North Atlantic: The Importance of Continental Margins

IF 5.4 2区 地球科学 Q1 ENVIRONMENTAL SCIENCES
Nolwenn Lemaitre, Marion Lagarde, Derek Vance
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Abstract

Copper (Cu) is a marine micronutrient whose distribution and budget remain incompletely understood. Here, we present a section of dissolved Cu isotope compositions (δ65Cu) across the North Atlantic (GEOVIDE cruise, GEOTRACES GA01). High δ65Cu are observed in surface waters and co-vary with carbon uptake rates, indicating light Cu removal by biological activity or complexation of heavy Cu by organic ligands. Beneath the surface, low δ65Cu may be partially caused by remineralization. Below 1,500 m, an increase in δ65Cu points to removal by particulate scavenging. At greater depths, reversible scavenging, driven by high vertical particulate exports, could explain the increase in Cu concentrations between the surface and deep ocean, mostly in the eastern part of the transect. Investigation of external sources and sinks reveals that anthropogenic aerosols and benthic processes locally supply isotopically light Cu to the ocean, whilst hydrothermal activity above the Reykjanes ridge does not seem to represent a significant source. A striking feature is the low δ65Cu observed between 300 and 1,500 m from the Iberian margin to the Icelandic basin, which coincides with elevated non-conservative dissolved neodymium fractions (Ndxs). This comparison suggests that margin inputs are a source of light Cu to the ocean, and that this Cu can be transported over long distances. The Iberian margin is a hotspot of internal tides and their energy triggers sediment resuspension, leading to particle dissolution and Cu release. These results suggest that continental margins contribute significantly to the missing source of light Cu in the ocean.

Abstract Image

北大西洋溶解铜浓度和同位素的控制:大陆边缘的重要性
铜(Cu)是一种海洋微量营养素,其分布和收支仍不完全清楚。在这里,我们展示了北大西洋溶解Cu同位素组成(δ65Cu)的剖面(GEOVIDE cruise, GEOTRACES GA01)。在地表水中观察到高δ65Cu,并随碳吸收率变化,表明生物活性去除轻Cu或有机配体络合重Cu。地表下低δ65Cu可能部分由再矿化作用引起。在1,500 m以下,δ65Cu的增加表明通过颗粒清除去除。在更深的深度,由高垂直颗粒出口驱动的可逆清除可以解释表层和深海之间铜浓度的增加,主要是在样带的东部。对外部源和汇的调查表明,人为气溶胶和底栖生物过程在局部向海洋提供同位素轻的铜,而雷克雅内斯脊上的热液活动似乎不是一个重要的来源。一个显著的特征是在伊比利亚边缘到冰岛盆地的300 ~ 1500 m之间观测到低δ65Cu,这与非保守性溶解钕组分(Ndxs)的升高相吻合。这一比较表明,边缘输入是光铜进入海洋的一个来源,并且这些铜可以长距离运输。伊比利亚边缘是内部潮汐的热点,它们的能量触发沉积物再悬浮,导致颗粒溶解和Cu释放。这些结果表明,大陆边缘对海洋中光Cu源的缺失有重要贡献。
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来源期刊
Global Biogeochemical Cycles
Global Biogeochemical Cycles 环境科学-地球科学综合
CiteScore
8.90
自引率
7.70%
发文量
141
审稿时长
8-16 weeks
期刊介绍: Global Biogeochemical Cycles (GBC) features research on regional to global biogeochemical interactions, as well as more local studies that demonstrate fundamental implications for biogeochemical processing at regional or global scales. Published papers draw on a wide array of methods and knowledge and extend in time from the deep geologic past to recent historical and potential future interactions. This broad scope includes studies that elucidate human activities as interactive components of biogeochemical cycles and physical Earth Systems including climate. Authors are required to make their work accessible to a broad interdisciplinary range of scientists.
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