Fluorination of sulfonyl hydrazides with fluorine gas for the synthesis of sulfonyl fluorides

IF 1.7 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Fluorine Chemistry Pub Date : 2025-04-01 DOI:10.1016/j.jfluchem.2025.110425

Zhou Yu , Sheng Wang , Wenbo Chen , Lele Wen , Long Lu

引用次数: 0

Abstract

An efficient method for synthesizing sulfonyl fluorides by fluorinating sulfonyl hydrazides with 10 % F₂/N₂ was developed. This transformation demonstrated a broad substrate scope, yielding a series of sulfonyl fluorides in moderate to good yields. Additionally, a 10 g scale experiment was conducted, demonstrating the practicality of this method.

Abstract Image

查看原文本刊更多论文

磺酰肼用氟气氟化合成磺酰氟

研究了以10% F2/N2氟化磺酰肼合成磺酰氟的有效方法。这一转变显示出广泛的底物范围，以中等到良好的产量生产一系列磺酰氟。并进行了10 g尺度的实验，验证了该方法的实用性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Fluorine Chemistry 化学-无机化学与核化学

CiteScore

3.80

自引率

10.50%

发文量

审稿时长

33 days

期刊介绍： The Journal of Fluorine Chemistry contains reviews, original papers and short communications. The journal covers all aspects of pure and applied research on the chemistry as well as on the applications of fluorine, and of compounds or materials where fluorine exercises significant effects. This can include all chemistry research areas (inorganic, organic, organometallic, macromolecular and physical chemistry) but also includes papers on biological/biochemical related aspects of Fluorine chemistry as well as medicinal, agrochemical and pharmacological research. The Journal of Fluorine Chemistry also publishes environmental and industrial papers dealing with aspects of Fluorine chemistry on energy and material sciences. Preparative and physico-chemical investigations as well as theoretical, structural and mechanistic aspects are covered. The Journal, however, does not accept work of purely routine nature. For reviews and special issues on particular topics of fluorine chemistry or from selected symposia, please contact the Regional Editors for further details.