Xin Qu , Ce Wang , Yuanyu Zhao , Jinqiu Ye , Ping Hu , Rui Zhao , Yong Liu
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引用次数: 0
Abstract
Human activities, ranging from medical applications to space exploration, face significant threats from multiband electromagnetic radiation. This challenge is particularly pronounced in the complex radiation environments of space. There is an urgent need for high-efficiency, stable broadband electromagnetic shielding materials to safeguard human health and equipment safety. Herein, a Bi-modified W18O49/MWCNTs/PAN hybrid nanofiber membrane is successfully prepared by electrospinning and post-treatment. Relying on the synergistic effect of Bi, W18O49, MWCNTs, and porous structures, excellent broadband radiation protection capability is achieved: (i) Low near-infrared-visible-light (NIR-VIS) transmittance (0.62 %); (ii) Ultraviolet (UV) transmittance of only 0.012 % and UPF value as high as 2000; (iii) Mass attenuation coefficient up to 16.18 cm2 g−1 and attenuation ratio of 85.74 % (thickness: 4 mm) at 33 keV X-ray energy. Furthermore, porous structure and high specific surface area give the membrane ultralight density (0.36 g cm−3), flexibility, and outstanding air permeability (8.5 kg m−2 d−1). Even after 2000 bends, it still maintains stable structure and performance. Meanwhile, low thermal conductivity (42.2 mW m−1 K−1) and superior temperature resistance (300 °C) enable it to adapt to complex and changing environments. These advantages make the membrane highly promising for radiation protection in medical, industrial, and aerospace applications.
期刊介绍:
Composites Science and Technology publishes refereed original articles on the fundamental and applied science of engineering composites. The focus of this journal is on polymeric matrix composites with reinforcements/fillers ranging from nano- to macro-scale. CSTE encourages manuscripts reporting unique, innovative contributions to the physics, chemistry, materials science and applied mechanics aspects of advanced composites.
Besides traditional fiber reinforced composites, novel composites with significant potential for engineering applications are encouraged.