Confinement-supported aurophilic interaction

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-28 DOI:10.1039/d5cc01540e

Youssoupha Diack, Sonia Mallet-Ladeira, Denis Lesage, Joao V. S. Guerra, Didier Bourissou, György Szalóki

引用次数: 0

Abstract

An anionic cyclotricatechylene cage (H) is shown (NMR, mass spectrometry and X-ray diffraction) to encapsulate cationic Au(I) complexes. As a result, an unprecedented bimetallic Au(I) complex (GG@H) has been characterized, in which confinement supports aurophilic interaction, even without bridging ligands.

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受限支持的亲金相互作用

通过核磁共振、质谱和x射线衍射发现，阴离子环三氯笼(H)可以包封阳离子Au(I)配合物。结果，一个前所未有的双金属Au(I)配合物（GG@H）被表征，其中约束支持亲金相互作用，即使没有桥接配体。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.