Frontispiz: Chiral Communication between Enantiomeric Sergeants and Achiral Soldiers in Racemic Triblock Copolymers with Heterochiral Cores for Triggering Multiple Helicity Inversions
{"title":"Frontispiz: Chiral Communication between Enantiomeric Sergeants and Achiral Soldiers in Racemic Triblock Copolymers with Heterochiral Cores for Triggering Multiple Helicity Inversions","authors":"Zixiang He, Haotian Ma, Zeyu Tang, Xiaoxiao Cheng, Prof. Wei Zhang","doi":"10.1002/ange.202581862","DOIUrl":null,"url":null,"abstract":"<p>A strategy for the racemic sergeants and soldiers (S&S) effect that achieved precise control over both the intensity and sign of global chirality was presented by Wei Zhang and co-workers in their Communication (e202500444). Distinct chiral communication pathways between enantiomeric sergeants and achiral soldiers in this racemic liquid crystalline S&S system were found to further in situ drive multiple transitions of chiroptical properties in racemic copolymer assemblies.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 18","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202581862","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202581862","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A strategy for the racemic sergeants and soldiers (S&S) effect that achieved precise control over both the intensity and sign of global chirality was presented by Wei Zhang and co-workers in their Communication (e202500444). Distinct chiral communication pathways between enantiomeric sergeants and achiral soldiers in this racemic liquid crystalline S&S system were found to further in situ drive multiple transitions of chiroptical properties in racemic copolymer assemblies.