Analysis of mass and thermal transport characteristics in a novel honeycomb stack layout of high-performance proton exchange membrane fuel cells

IF 8.1 2区 工程技术 Q1 CHEMISTRY, PHYSICAL
Qingshan Liu , Qingshuai Zhao , Shixin Li , Jiakun Si , Pei Fu , Rong Huang , Geng Luo , Qiming Li , Yong Zhang , Yisong Chen
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Abstract

To rationalize the layout of the fuel cell (FC) power system within the limited on-board space and enhance its volumetric power density, a novel honeycomb layout of the stack is designed in this study. This layout connects the individual FCs in the form of sidewalls, which reduces the longitudinal size by 59.5 % compared with the conventional stack with top and bottom terminals connected. To conduct a detailed comparison of the spatial distribution characteristics of physical quantities within each single FC in the two stack layouts, a three-dimensional multiphase non-isothermal model is developed, which focuses on the influence of the random microporous structure of the porous layer on the heat-mass transfer and the electrochemical reaction process, making the results more realistic. The results show that relative to the original stack, the novel stack layout shortens the inter-FC conductive path and increases the heat dissipation area. Therefore, the ohmic polarization region is extended and the concentration polarization region is shortened, which increased the peak power density by 5.1 %. The placement of single FCs strongly affects the spatial distribution of internal physical quantities and performance, with FCs placed at an angle of −30° to the horizontal having the best performance.
高性能质子交换膜燃料电池新型蜂窝堆布局的质量和热输运特性分析
为了在有限的车载空间内优化燃料电池动力系统的布局,提高燃料电池动力系统的体积功率密度,设计了一种新型的蜂窝结构。这种布局以侧壁的形式连接各个fc,与传统的顶部和底部终端连接的堆叠相比,减少了59.5%的纵向尺寸。为了详细比较两种堆叠布局下单个FC内物理量的空间分布特征,建立了三维多相非等温模型,重点研究了多孔层的随机微孔结构对传热传质和电化学反应过程的影响,使结果更加真实。结果表明,相对于原堆叠,新型堆叠缩短了fc间的传导路径,增加了散热面积。因此,欧姆极化区扩大,浓极化区缩短,峰值功率密度提高了5.1%。单个fc的放置对内部物理量的空间分布和性能影响较大,与水平面成- 30°夹角放置的fc性能最佳。
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来源期刊
International Journal of Hydrogen Energy
International Journal of Hydrogen Energy 工程技术-环境科学
CiteScore
13.50
自引率
25.00%
发文量
3502
审稿时长
60 days
期刊介绍: The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc. The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.
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