Lin XING , Wei ZHOU , Kai-xiong XIANG , Wei-na DENG , Liang CHEN , Hai ZHU , Han CHEN
{"title":"Preparation of (NH4)2V6O16·1.5H2O nanoribbons and their application in aqueous ammonium-ion batteries","authors":"Lin XING , Wei ZHOU , Kai-xiong XIANG , Wei-na DENG , Liang CHEN , Hai ZHU , Han CHEN","doi":"10.1016/S1003-6326(24)66749-X","DOIUrl":null,"url":null,"abstract":"<div><div>To construct high-performance aqueous ammonium-ion full batteries, (NH<sub>4</sub>)<sub>2</sub>V<sub>6</sub>O<sub>16</sub>·1.5H<sub>2</sub>O (NVO) nanoribbon cathodes were prepared by pH-regulated hydrothermal synthesis. Anodes were prepared by growing the active material polyaniline (PANI) on carbon cloth. The assembled NVO<strong>//</strong>PANI full cells exhibit a reversible capacity of 109.5 mA·h/g at a current density of 1.0 A/g and a high energy density of 23 W·h/kg. The ammonium-ion intercalation/extraction mechanism is primarily governed by the pseudocapacitance behavior. These results indicate that NVO is a potential candidate as a cathode material for aqueous ammonium-ion batteries.</div></div>","PeriodicalId":23191,"journal":{"name":"Transactions of Nonferrous Metals Society of China","volume":"35 4","pages":"Pages 1292-1305"},"PeriodicalIF":4.7000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of Nonferrous Metals Society of China","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S100363262466749X","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
Abstract
To construct high-performance aqueous ammonium-ion full batteries, (NH4)2V6O16·1.5H2O (NVO) nanoribbon cathodes were prepared by pH-regulated hydrothermal synthesis. Anodes were prepared by growing the active material polyaniline (PANI) on carbon cloth. The assembled NVO//PANI full cells exhibit a reversible capacity of 109.5 mA·h/g at a current density of 1.0 A/g and a high energy density of 23 W·h/kg. The ammonium-ion intercalation/extraction mechanism is primarily governed by the pseudocapacitance behavior. These results indicate that NVO is a potential candidate as a cathode material for aqueous ammonium-ion batteries.
期刊介绍:
The Transactions of Nonferrous Metals Society of China (Trans. Nonferrous Met. Soc. China), founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, INSPEC, CA, METADEX, AJ and JICST.