Facile and Low-Cost Design Alternative of Spiro-OMeTAD as p-Type Semiconductor for Efficient Perovskite Solar Cells

IF 6 3区 工程技术 Q2 ENERGY & FUELS
Solar RRL Pub Date : 2025-03-10 DOI:10.1002/solr.202500034
Sarune Daskeviciute, Yi Zhang, Maryte Daskeviciene, Kasparas Rakstys, Julius Petrulevicius, Vygintas Jankauskas, Vytautas Getautis, Mohammad Khaja Nazeeruddin
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引用次数: 0

Abstract

A simple diphenylamine-based hole transporting material V1553 was synthesized and incorporated into a perovskite solar cell, which showed remarkable power conversion efficiency close to 23%. The investigated HTM was synthesized via one-step catalyst-free condensation reaction from commercially available and extremely cheap starting reagents, resulting in a fractional cost of the final product compared to the commercial spiro-OMeTAD. This material promises to be a viable p-type organic semiconductor to be employed in the manufacturing of perovskite solar modules.

Abstract Image

高效钙钛矿太阳能电池中用作p型半导体的Spiro-OMeTAD的简单低成本设计选择
合成了一种简单的二苯胺基空穴传输材料V1553,并将其加入到钙钛矿太阳能电池中,其功率转换效率接近23%。所研究的HTM是通过一步无催化剂缩合反应合成的,原料是市售的、非常便宜的起始试剂,与市售的螺旋- ometad相比,最终产品的成本很低。这种材料有望成为一种可行的p型有机半导体,用于制造钙钛矿太阳能组件。
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来源期刊
Solar RRL
Solar RRL Physics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
12.10
自引率
6.30%
发文量
460
期刊介绍: Solar RRL, formerly known as Rapid Research Letters, has evolved to embrace a broader and more encompassing format. We publish Research Articles and Reviews covering all facets of solar energy conversion. This includes, but is not limited to, photovoltaics and solar cells (both established and emerging systems), as well as the development, characterization, and optimization of materials and devices. Additionally, we cover topics such as photovoltaic modules and systems, their installation and deployment, photocatalysis, solar fuels, photothermal and photoelectrochemical solar energy conversion, energy distribution, grid issues, and other relevant aspects. Join us in exploring the latest advancements in solar energy conversion research.
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