Synthesis of 5-hydroxymethylfurfural and its oxidation derivatives by immobilized catalysts: An efficient green sustainable technology

IF 15.7 1区化学 Q1 CHEMISTRY, APPLIED

Chinese Journal of Catalysis Pub Date : 2025-04-01 DOI:10.1016/S1872-2067(24)60274-3

Yao Chen , Jun Ge

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引用次数: 0

Abstract

5-Hydroxymethylfurfural (HMF) and its oxidation derivatives have emerged as a bridge between biomass resources and the future energy industry. These renewable biomass resources can be transformed into a variety of value-added chemicals, thereby addressing the challenges posed by diminishing fossil fuel reserves and environmental concerns. The immobilization of catalysts represents an innovative method for the sustainable and efficient synthesis of HMF and its oxidation derivatives. This method not only enhances the yield and selectivity of the products but also allows for the optimization of the catalytic performance of immobilized catalysts through the strategic design of their supports. In this review, we provide an overview of the recent advancements in the technology of immobilized catalyst and its application in the synthesis of HMF and its oxidation derivatives, with a particular focus on the preparation and catalytic characteristics of these immobilized catalysts. Furthermore, we discuss potential future directions for the development of immobilized catalysts, including the preparation of high-performance immobilized catalysts, the exploration of their growth and catalytic mechanisms, and the economic implications of raw material utilization. This area of research presents both significant promise and considerable challenges.

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利用固定化催化剂合成 5-羟甲基糠醛及其氧化衍生物：一种高效的绿色可持续技术

5-羟甲基糠醛（HMF）及其氧化衍生物已成为连接生物质资源和未来能源产业的桥梁。这些可再生生物质资源可以转化为各种增值化学品，从而解决化石燃料储量减少和环境问题带来的挑战。固定化催化剂是可持续高效合成HMF及其氧化衍生物的一种创新方法。该方法不仅提高了产物的产率和选择性，而且可以通过对固定化催化剂载体的战略性设计来优化其催化性能。本文综述了固定化催化剂技术的最新进展及其在HMF及其氧化衍生物合成中的应用，重点介绍了固定化催化剂的制备方法和催化性能。此外，我们还讨论了固定化催化剂的潜在发展方向，包括高性能固定化催化剂的制备，其生长和催化机理的探索，以及原料利用的经济意义。这一领域的研究既有重大的前景，也有相当大的挑战。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chinese Journal of Catalysis 工程技术-工程：化工

CiteScore

25.80

自引率

10.30%

发文量

235

审稿时长

1.2 months

期刊介绍： The journal covers a broad scope, encompassing new trends in catalysis for applications in energy production, environmental protection, and the preparation of materials, petroleum chemicals, and fine chemicals. It explores the scientific foundation for preparing and activating catalysts of commercial interest, emphasizing representative models.The focus includes spectroscopic methods for structural characterization, especially in situ techniques, as well as new theoretical methods with practical impact in catalysis and catalytic reactions.The journal delves into the relationship between homogeneous and heterogeneous catalysis and includes theoretical studies on the structure and reactivity of catalysts.Additionally, contributions on photocatalysis, biocatalysis, surface science, and catalysis-related chemical kinetics are welcomed.