Research progress on metal-support interactions over Ni-based catalysts for CH4-CO2 reforming reaction

Q3 Energy

燃料化学学报 Pub Date : 2025-04-01 DOI:10.1016/S1872-5813(24)60500-1

Kai SUN, Jianfei JIANG, Zixuan LIU, Shiqi GENG, Zhenmin LIU, Jiaqian YANG, Shasha LI

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引用次数: 0

Abstract

With ongoing global warming and increasing energy demands, the CH₄-CO₂ reforming reaction (dry reforming of methane, DRM) has garnered significant attention as a promising carbon capture and utilization technology. Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process. The impact of metal-support interaction (MSI), on Ni-based catalyst performance has been extensively researched and debated recently. This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions. From the perspective of MSI, the effects of different carriers (metal oxides, carbon materials and molecular sieves, etc.) are introduced on the dispersion and surface structure of Ni active metal particles, and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail. Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH₄-CO₂ reforming, advancing cleaner energy technologies.

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ni基催化剂上金属-载体相互作用对CH4-CO2重整反应的研究进展

随着全球变暖和能源需求的增加，CH4-CO2重整反应（甲烷干重整，DRM）作为一种有前景的碳捕获与利用技术受到了广泛关注。镍基催化剂在这一过程中以其出色的活性和选择性而闻名。金属-载体相互作用（MSI）对镍基催化剂性能的影响近年来得到了广泛的研究和争论。本文综述了镍基催化剂上MSI的研究进展及其在催化反应中的表征和调制策略。从MSI的角度，介绍了不同载体（金属氧化物、碳材料和分子筛等）对Ni活性金属颗粒的分散和表面结构的影响，并详细讨论了MSI对Ni基催化剂上DRM反应活性和稳定性的影响。未来的研究应着眼于更好地了解和控制MSI，以提高镍基催化剂在CH4-CO2重整中的性能和耐久性，推进清洁能源技术的发展。

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来源期刊

燃料化学学报 Chemical Engineering-Chemical Engineering (all)

CiteScore

2.80

自引率

0.00%

发文量

5825

期刊介绍： Journal of Fuel Chemistry and Technology (Ranliao Huaxue Xuebao) is a Chinese Academy of Sciences(CAS) journal started in 1956, sponsored by the Chinese Chemical Society and the Institute of Coal Chemistry, Chinese Academy of Sciences(CAS). The journal is published bimonthly by Science Press in China and widely distributed in about 20 countries. Journal of Fuel Chemistry and Technology publishes reports of both basic and applied research in the chemistry and chemical engineering of many energy sources, including that involved in the nature, processing and utilization of coal, petroleum, oil shale, natural gas, biomass and synfuels, as well as related subjects of increasing interest such as C1 chemistry, pollutions control and new catalytic materials. Types of publications include original research articles, short communications, research notes and reviews. Both domestic and international contributors are welcome. Manuscripts written in Chinese or English will be accepted. Additional English titles, abstracts and key words should be included in Chinese manuscripts. All manuscripts are subject to critical review by the editorial committee, which is composed of about 10 foreign and 50 Chinese experts in fuel science. Journal of Fuel Chemistry and Technology has been a source of primary research work in fuel chemistry as a Chinese core scientific periodical.