Rapid Regeneration of Spent FCC Catalysts through Selective Bioleaching by the Spent Medium Process

IF 3.7 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Shihao Zhang,  and , Baoping Xin*, 
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引用次数: 0

Abstract

Fluid catalytic cracking (FCC) catalysts play an important role in modern industrial production and are capable of converting heavy oils into light oils. However, in the process of long-term use, the FCC catalyst will reduce its activity due to internal wear and external factors, and it will become a spent catalyst after failing to meet the requirements of use. Approximately one million tons of spent FCC catalysts are generated annually, and improper disposal of this hazardous waste can pose significant harm. In this study, the spent catalyst is treated by the bioleaching method, which restored its activity to some extent, allowing for its reuse in industrial production. This study found that at 58 °C, the biological cleaning of spent catalyst with 5.6% pulp density can increase its activity by about 10%, whereas the corresponding treatment with a mixed acid only achieved a 2% increase. This demonstrates the feasibility of the bioleaching method and provides insights into further enhancing the activity of spent catalysts.

废介质选择性生物浸出法快速再生FCC催化剂
流体催化裂化催化剂在现代工业生产中起着重要的作用,它能将重油转化为轻质油。但FCC催化剂在长期使用过程中,会因内部磨损和外界因素导致活性降低,达不到使用要求后成为废催化剂。每年大约产生100万吨催化裂化催化剂废料,不当处理这些危险废物会造成重大危害。本研究对废催化剂进行了生物浸出处理,在一定程度上恢复了催化剂的活性,使其可以在工业生产中重复使用。本研究发现,在58℃下,用5.6%浆密度的废催化剂进行生物清洗可使其活性提高约10%,而用混合酸进行相应处理仅能提高2%。这证明了生物浸出方法的可行性,并为进一步提高废催化剂的活性提供了见解。
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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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