{"title":"A short-term durability comprehensive study of ceramic waste-doped White Cement composites with hooked-end, basalt and copper-coated fibers","authors":"Baraa Abduljabbar Badi Al-Sharhanee , Metin Mehmetoğlu , Yurdakul Aygörmez , Anıl Niş","doi":"10.1016/j.scp.2025.102026","DOIUrl":null,"url":null,"abstract":"<div><div>White Cement (WC) mixes are an alternative product to the OPC. However, there are limited studies on the materials used in the production of composite materials as substitutes for the WC. Ceramic waste (CW) is an important alternative material in this regard. In this context, ceramic waste was replaced with White Cement at the rates of 5 %, 10 %, and 15 %, while three different fibers for reinforcement, namely hooked-end (HE) steel fiber, basalt (B) fiber, and copper-coated (CC) steel fiber (0.4 %) were used. The compressive and flexural strength results at 28 and 90 days were examined for the variations of White cement-based mortar properties. After 90 days, durability tests (sulfate effect, high temperature, and freeze-thaw) were applied while mechanical properties and weight losses were measured. SEM, XRD, Micro-CT, and TGA-DTA analyses were also used to see the changes with durability tests. According to the results, the increase in SiO<sub>2</sub> and Al<sub>2</sub>O<sub>3</sub> content in the addition of 5 % and 10 % ceramic waste increased the strength while keeping the pozzolanic reaction at a high level. In the case of 15 % substitution, it caused a reduction due to the decrease in the cement's relative content. The hooked-end steel fiber, which was denser and longer, had the highest performance, while the copper-coated steel fiber showed the lowest performance. With 5 % ceramic powder and hooked-end steel fiber reinforcement, the flexural strength was enhanced by 26 %, while the compressive strength was enhanced by 17 % compared to the 100 % White Cement sample (control sample).</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"45 ","pages":"Article 102026"},"PeriodicalIF":5.5000,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sustainable Chemistry and Pharmacy","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S235255412500124X","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
White Cement (WC) mixes are an alternative product to the OPC. However, there are limited studies on the materials used in the production of composite materials as substitutes for the WC. Ceramic waste (CW) is an important alternative material in this regard. In this context, ceramic waste was replaced with White Cement at the rates of 5 %, 10 %, and 15 %, while three different fibers for reinforcement, namely hooked-end (HE) steel fiber, basalt (B) fiber, and copper-coated (CC) steel fiber (0.4 %) were used. The compressive and flexural strength results at 28 and 90 days were examined for the variations of White cement-based mortar properties. After 90 days, durability tests (sulfate effect, high temperature, and freeze-thaw) were applied while mechanical properties and weight losses were measured. SEM, XRD, Micro-CT, and TGA-DTA analyses were also used to see the changes with durability tests. According to the results, the increase in SiO2 and Al2O3 content in the addition of 5 % and 10 % ceramic waste increased the strength while keeping the pozzolanic reaction at a high level. In the case of 15 % substitution, it caused a reduction due to the decrease in the cement's relative content. The hooked-end steel fiber, which was denser and longer, had the highest performance, while the copper-coated steel fiber showed the lowest performance. With 5 % ceramic powder and hooked-end steel fiber reinforcement, the flexural strength was enhanced by 26 %, while the compressive strength was enhanced by 17 % compared to the 100 % White Cement sample (control sample).
期刊介绍:
Sustainable Chemistry and Pharmacy publishes research that is related to chemistry, pharmacy and sustainability science in a forward oriented manner. It provides a unique forum for the publication of innovative research on the intersection and overlap of chemistry and pharmacy on the one hand and sustainability on the other hand. This includes contributions related to increasing sustainability of chemistry and pharmaceutical science and industries itself as well as their products in relation to the contribution of these to sustainability itself. As an interdisciplinary and transdisciplinary journal it addresses all sustainability related issues along the life cycle of chemical and pharmaceutical products form resource related topics until the end of life of products. This includes not only natural science based approaches and issues but also from humanities, social science and economics as far as they are dealing with sustainability related to chemistry and pharmacy. Sustainable Chemistry and Pharmacy aims at bridging between disciplines as well as developing and developed countries.