{"title":"Effect of pressure on the oil shale convection heating in-situ conversion process","authors":"Tanen Jiang , Lihong Yang , Chaofan Zhu","doi":"10.1016/j.ijthermalsci.2025.109940","DOIUrl":null,"url":null,"abstract":"<div><div>In-situ conversion technology represents the developmental trend for large-scale commercial exploitation of oil shale. High-pressure geological conditions significantly influence the pyrolysis kinetics of oil shale and the in-situ extraction process. This study conducted pyrolysis experiments on Qingshankou Formation oil shale from the Songliao Basin under varying nitrogen pressures, analyzing temperature fields, pressure fields, and oil production. Concurrently, CMG software was employed to simulate the in-situ extraction process through high-temperature nitrogen injection, evaluating the impact of pressure variations on extraction effectiveness from perspectives of reservoir properties, product yield, and energy utilization efficiency. Laboratory results indicated that increased pressure led to higher reaction temperatures and thermal losses, which would be expected to reduce the oil yield, but higher pressure reduced the risk of reservoir plugging, so that the observed oil yield was higher at higher pressure. Numerical simulations revealed distinct pyrolysis kinetics under high pressure compared to atmospheric conditions, showing elevated activation energy and reduced conversion rates with pressure increase. During high-temperature nitrogen injection, cumulative oil production and energy efficiency decreased under higher pressures. Consequently, the simulation indicates that excessive pressure inhibits the effectiveness of convection.</div></div>","PeriodicalId":341,"journal":{"name":"International Journal of Thermal Sciences","volume":"214 ","pages":"Article 109940"},"PeriodicalIF":4.9000,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Thermal Sciences","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1290072925002637","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, MECHANICAL","Score":null,"Total":0}
引用次数: 0
Abstract
In-situ conversion technology represents the developmental trend for large-scale commercial exploitation of oil shale. High-pressure geological conditions significantly influence the pyrolysis kinetics of oil shale and the in-situ extraction process. This study conducted pyrolysis experiments on Qingshankou Formation oil shale from the Songliao Basin under varying nitrogen pressures, analyzing temperature fields, pressure fields, and oil production. Concurrently, CMG software was employed to simulate the in-situ extraction process through high-temperature nitrogen injection, evaluating the impact of pressure variations on extraction effectiveness from perspectives of reservoir properties, product yield, and energy utilization efficiency. Laboratory results indicated that increased pressure led to higher reaction temperatures and thermal losses, which would be expected to reduce the oil yield, but higher pressure reduced the risk of reservoir plugging, so that the observed oil yield was higher at higher pressure. Numerical simulations revealed distinct pyrolysis kinetics under high pressure compared to atmospheric conditions, showing elevated activation energy and reduced conversion rates with pressure increase. During high-temperature nitrogen injection, cumulative oil production and energy efficiency decreased under higher pressures. Consequently, the simulation indicates that excessive pressure inhibits the effectiveness of convection.
期刊介绍:
The International Journal of Thermal Sciences is a journal devoted to the publication of fundamental studies on the physics of transfer processes in general, with an emphasis on thermal aspects and also applied research on various processes, energy systems and the environment. Articles are published in English and French, and are subject to peer review.
The fundamental subjects considered within the scope of the journal are:
* Heat and relevant mass transfer at all scales (nano, micro and macro) and in all types of material (heterogeneous, composites, biological,...) and fluid flow
* Forced, natural or mixed convection in reactive or non-reactive media
* Single or multi–phase fluid flow with or without phase change
* Near–and far–field radiative heat transfer
* Combined modes of heat transfer in complex systems (for example, plasmas, biological, geological,...)
* Multiscale modelling
The applied research topics include:
* Heat exchangers, heat pipes, cooling processes
* Transport phenomena taking place in industrial processes (chemical, food and agricultural, metallurgical, space and aeronautical, automobile industries)
* Nano–and micro–technology for energy, space, biosystems and devices
* Heat transport analysis in advanced systems
* Impact of energy–related processes on environment, and emerging energy systems
The study of thermophysical properties of materials and fluids, thermal measurement techniques, inverse methods, and the developments of experimental methods are within the scope of the International Journal of Thermal Sciences which also covers the modelling, and numerical methods applied to thermal transfer.