Synthesis and Evaluation of 3D Nitrogen Doped Reduced Graphene Oxide (3D N@rGO) Macrostructure for Boosted Solar Driven Interfacial Desalination of Saline Water

Abstract

Recently, there has been a growing interest in solar-driven interfacial desalination technology, which focuses on the localization of heat to the air-water interface. In this study, 3D nitrogen-doped reduced graphene oxide (3D N@rGO) photothermal material is synthesized with a facile one-step hydrothermal process. The material exhibited richer porosity, high hydrophilicity for efficient water channeling, and all-directional solar absorption potential. The 3D N@rGO solar absorber attained up to ≈55 °C surface temperature rise and showed ≈134% photothermal conversion efficiency with 1.94 kg m⁻² h⁻¹ net freshwater generation rate under 1 sun solar illumination, owing to efficient latent heat recycle. On a high salinity desalination study performed using 10 and 20 wt.% salinity levels, the photothermal material showed 1.66 and 1.31 kg m⁻² h⁻¹ evaporation rates respectively. It sustained stable long-term desalination performance without visible salt accumulation on the surface up to a salinity level of 10 wt.%. In a three-day outdoor test carried out utilizing simulated seawater with a 3.5 wt.% NaCl solution, the 3D evaporator demonstrated an average freshwater production rate of 2.61 kg m⁻² h⁻¹, during the test the solar power density reached up to 1.1 kW m⁻². The 3D solar absorber exhibited a promising potential for large-scale seawater desalination in water-scarce regions worldwide.