Hydrogen Sensor for LIB Thermal Runaway Based on Ag-Bi-Modified Co3O4 Nanosheets: Experimental and DFT Calculation

IF 4.3 2区综合性期刊 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC

IEEE Sensors Journal Pub Date : 2025-03-14 DOI:10.1109/JSEN.2025.3547937

Yong Zhang;Jieshuo Zhai;Peilin Jia;Xingyan Shao;Xinyi Ji;Gongao Jiao;Dongzhi Zhang

{"title":"Hydrogen Sensor for LIB Thermal Runaway Based on Ag-Bi-Modified Co3O4 Nanosheets: Experimental and DFT Calculation","authors":"Yong Zhang;Jieshuo Zhai;Peilin Jia;Xingyan Shao;Xinyi Ji;Gongao Jiao;Dongzhi Zhang","doi":"10.1109/JSEN.2025.3547937","DOIUrl":null,"url":null,"abstract":"Hydrogen (H2) is a typical gas generated by the thermal runaway (TR) fault of lithium-ion batteries (LIBs) and a typical gas for TR fault diagnosis. Fast detection and high sensitivity of hydrogen sensors have practical significance. In this article, the hydrothermal method was used to prepare Co3O4 nanosheets, and Ag- and Bi-modified Co3O4 composite was also successfully prepared. X-ray diffraction (XRD), scanning electron microscopy (SEM), TEM, and X-ray photoelectron spectroscopy (XPS) were used to characterize and analyze the crystalline phase structure, micromorphology, and physical equality properties of the material. Then the gas sensing properties of AgBi/Co3O4 composite on H2 were investigated. The experimental results showed that the optimum operating temperature of the AgBi/Co3O4 sensor for H2 is <inline-formula> <tex-math>$160~^{\\circ }$ </tex-math></inline-formula>C. At this temperature, the AgBi/Co3O4 sensor has the best hydrogen sensing performance, with a response value of 2.6–400 ppm H2 and a response recovery time of 19/13 s, in addition, it has good stability and selectivity. Through first-principles calculation, the sensing mechanism of AgBi/Co3O4 was further explored. The results showed that the enhancement of AgBi/Co3O4 hydrogen sensing performance was the result of the synergistic catalytic action of Ag and Bi bimetals.","PeriodicalId":447,"journal":{"name":"IEEE Sensors Journal","volume":"25 8","pages":"12599-12608"},"PeriodicalIF":4.3000,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IEEE Sensors Journal","FirstCategoryId":"103","ListUrlMain":"https://ieeexplore.ieee.org/document/10925567/","RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}

引用次数: 0

Abstract

Hydrogen (H2) is a typical gas generated by the thermal runaway (TR) fault of lithium-ion batteries (LIBs) and a typical gas for TR fault diagnosis. Fast detection and high sensitivity of hydrogen sensors have practical significance. In this article, the hydrothermal method was used to prepare Co3O4 nanosheets, and Ag- and Bi-modified Co3O4 composite was also successfully prepared. X-ray diffraction (XRD), scanning electron microscopy (SEM), TEM, and X-ray photoelectron spectroscopy (XPS) were used to characterize and analyze the crystalline phase structure, micromorphology, and physical equality properties of the material. Then the gas sensing properties of AgBi/Co3O4 composite on H2 were investigated. The experimental results showed that the optimum operating temperature of the AgBi/Co3O4 sensor for H2 is

$160~^{\circ }$

C. At this temperature, the AgBi/Co3O4 sensor has the best hydrogen sensing performance, with a response value of 2.6–400 ppm H2 and a response recovery time of 19/13 s, in addition, it has good stability and selectivity. Through first-principles calculation, the sensing mechanism of AgBi/Co3O4 was further explored. The results showed that the enhancement of AgBi/Co3O4 hydrogen sensing performance was the result of the synergistic catalytic action of Ag and Bi bimetals.

查看原文本刊更多论文

基于ag - bi修饰Co3O4纳米片的LIB热失控氢传感器：实验与DFT计算

氢气（H2）是锂离子电池热失控（TR）故障产生的典型气体，也是TR故障诊断的典型气体。氢传感器的快速检测和高灵敏度具有重要的现实意义。本文采用水热法制备了Co3O4纳米片，并成功制备了Ag和bi修饰的Co3O4复合材料。采用x射线衍射（XRD）、扫描电镜（SEM）、透射电镜（TEM）和x射线光电子能谱（XPS）对材料的晶相结构、微观形貌和物理均匀性进行了表征和分析。然后研究了AgBi/Co3O4复合材料在H2上的气敏性能。实验结果表明，AgBi/Co3O4传感器对H2的最佳工作温度为$160~ $ {\circ}$ c，在此温度下，AgBi/Co3O4传感器具有最佳的氢传感性能，响应值为2.6 ~ 400 ppm H2，响应恢复时间为19/13 s，并且具有良好的稳定性和选择性。通过第一性原理计算，进一步探讨了AgBi/Co3O4的传感机理。结果表明，AgBi/Co3O4感氢性能的增强是Ag和Bi双金属协同催化作用的结果。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

IEEE Sensors Journal 工程技术-工程：电子与电气

CiteScore

7.70

自引率

14.00%

发文量

2058

审稿时长

5.2 months

期刊介绍： The fields of interest of the IEEE Sensors Journal are the theory, design , fabrication, manufacturing and applications of devices for sensing and transducing physical, chemical and biological phenomena, with emphasis on the electronics and physics aspect of sensors and integrated sensors-actuators. IEEE Sensors Journal deals with the following: -Sensor Phenomenology, Modelling, and Evaluation -Sensor Materials, Processing, and Fabrication -Chemical and Gas Sensors -Microfluidics and Biosensors -Optical Sensors -Physical Sensors: Temperature, Mechanical, Magnetic, and others -Acoustic and Ultrasonic Sensors -Sensor Packaging -Sensor Networks -Sensor Applications -Sensor Systems: Signals, Processing, and Interfaces -Actuators and Sensor Power Systems -Sensor Signal Processing for high precision and stability (amplification, filtering, linearization, modulation/demodulation) and under harsh conditions (EMC, radiation, humidity, temperature); energy consumption/harvesting -Sensor Data Processing (soft computing with sensor data, e.g., pattern recognition, machine learning, evolutionary computation; sensor data fusion, processing of wave e.g., electromagnetic and acoustic; and non-wave, e.g., chemical, gravity, particle, thermal, radiative and non-radiative sensor data, detection, estimation and classification based on sensor data) -Sensors in Industrial Practice