Fullerene Network-Buffered Platinum Nanoparticles Towards Efficient and Stable Electrochemical Ammonia Oxidation Reaction for Hydrogen Production

IF 16.1 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Angewandte Chemie International Edition Pub Date : 2025-04-16 DOI:10.1002/anie.202505180

Xiang Chen, Zhongyuan Ke, Xing Wang, Hongqiang Jin, Yuwen Cheng, Yukun Xiao, Rui Jiang, Yumin Da, Lei Fan, Hexing Li, Dongming Liu, Shangfeng Yang, Wei Chen

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引用次数: 0

Abstract

Green ammonia is a promising hydrogen carrier due to its well-established production, storage, and transportation infrastructure. Moreover, hydrogen production via electrochemical ammonia oxidation reaction (AOR) requires a significantly lower theoretical potential than water electrolysis. However, the sluggish kinetics and poor stability of AOR hinder the industrial application of ammonia electrolysis. Herein, we report the construction of two-dimensional covalently bonded fullerene polymeric network (PNW-C60) supported platinum nanoparticles (Pt NPs) as a highly active and stable AOR electrocatalyst. The unique electron buffering effect of PNW-C60 enhances the desorption of nitrogen-containing species and prevents their poisoning on the Pt NPs surface. Consequently, the as-obtained PNW-C60-buffered Pt NPs exhibits a high mass activity of 118 A gPt-1 as well as good stability, outperforming commercial Pt/C and graphene-supported Pt NPs AOR catalysts.

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来源期刊

Angewandte Chemie International Edition 化学-化学综合

CiteScore

26.60

自引率

6.60%

发文量

3549

审稿时长

1.5 months

期刊介绍： Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.