Principles of the Injection of Organic Substances into a Gas Chromatographic Column by Thermal Desorption Depending on the Volatility of the Mixture Components

IF 1 4区 化学 Q4 CHEMISTRY, ANALYTICAL
M. N. Baldin, V. M. Gruznov, V. V. Fedotov
{"title":"Principles of the Injection of Organic Substances into a Gas Chromatographic Column by Thermal Desorption Depending on the Volatility of the Mixture Components","authors":"M. N. Baldin,&nbsp;V. M. Gruznov,&nbsp;V. V. Fedotov","doi":"10.1134/S106193482470148X","DOIUrl":null,"url":null,"abstract":"<p>A review of methods for thermal desorption from concentrators in portable rapid gas chromatographs of the EKhO series for injecting samples of organic substances into a gas chromatographic column depending on the volatility range of substances in the samples is presented. Sample injection techniques without manual operations in EKhO instruments are considered. The principles of sample injection with incomplete gas-dynamic isolation of the injection chamber and the column when introducing explosive and arene vapor samples with different volatility of substances in the sample and with complete isolation of the injection chamber and the column when introducing samples of C<sub>1</sub>−C<sub>5</sub> saturated hydrocarbons with sharply different volatility are described.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"15 - 23"},"PeriodicalIF":1.0000,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Analytical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S106193482470148X","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0

Abstract

A review of methods for thermal desorption from concentrators in portable rapid gas chromatographs of the EKhO series for injecting samples of organic substances into a gas chromatographic column depending on the volatility range of substances in the samples is presented. Sample injection techniques without manual operations in EKhO instruments are considered. The principles of sample injection with incomplete gas-dynamic isolation of the injection chamber and the column when introducing explosive and arene vapor samples with different volatility of substances in the sample and with complete isolation of the injection chamber and the column when introducing samples of C1−C5 saturated hydrocarbons with sharply different volatility are described.

根据混合物成分的挥发性,通过热脱附将有机物注入气相色谱柱的原理
根据样品中物质的挥发性范围,介绍了EKhO系列便携式快速气相色谱仪的浓缩器热解吸方法,用于将有机物质样品注入气相色谱仪柱中。考虑了在EKhO仪器中无需人工操作的样品进样技术。介绍了在引入挥发性不同的爆炸性和芳烃蒸气样品时,进样室和色谱柱不完全气动力隔离的进样原理,以及在引入挥发性差别很大的C1 ~ C5饱和烃样品时,进样室和色谱柱完全隔离的进样原理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of Analytical Chemistry
Journal of Analytical Chemistry 化学-分析化学
CiteScore
2.10
自引率
9.10%
发文量
146
审稿时长
13 months
期刊介绍: The Journal of Analytical Chemistry is an international peer reviewed journal that covers theoretical and applied aspects of analytical chemistry; it informs the reader about new achievements in analytical methods, instruments and reagents. Ample space is devoted to problems arising in the analysis of vital media such as water and air. Consideration is given to the detection and determination of metal ions, anions, and various organic substances. The journal welcomes manuscripts from all countries in the English or Russian language.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信