Correction to “Deoxygenation of 1° and 2° Amides with Ce[N(SiMe3)2]3(THF)3 under Mild Conditions”

Abstract

The Ce[N(SiMe₃)₂]₃(THF)₃ should be read as Ce[N(SiMe₃)₂]₃ in this work. There is no THF coordinated with the cerium center as per the analytical data and the molecular structure provided in the corrected Supporting Information. The stoichiometric reactions (Scheme 9) are also repeated, and revised spectra are provided in the corrected Supporting Information. All the catalytic reactions are repeated with the Ce[N(SiMe₃)₂]₃ as per the mol % calculation mentioned in the previous submission, and there is no significant change in the yields. The following text should be added on page 13583 under the subheading of EXPERIMENTAL MECHANISTIC ASPECTS: “The ¹H NMR spectrum of this mixture was inconclusive, but a small peak at 581.6802 was observed in the mass spectrum of a 1:1 mixture of Ce[N(SiMe₃)₂]₃ with benzamide, which corresponds to the cerium mono-amidate complex.” The following text should be added on page 13583 under the subheading of EXPERIMENTAL MECHANISTIC ASPECTS: “The mass spectrometric data showed an intense peak at m/z 501.1758, which matches well with the mass of the cerium tris-amidate complex of benzamide (Figure S51).” The following text should be added in the footnote of Scheme 6: ^aYields were determined by integrating ¹H NMR spectra in the presence of an internal standard (mesitylene). ^bReaction time of 24 h. ^cCatalyst (1 mol %) and 4 h reaction time. ^d2b, 2d , and 2g require high temperature (∼100 °C) and 24 h reaction time. The following text should be added in the footnote of Scheme 7: ^aYields were determined by integrating ¹H NMR spectra in the presence of an internal standard (mesitylene). ^b2j and 2n require high temperature (∼100 °C) and 24 h reaction time. The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acscatal.5c02346. Experimental procedures and characterization data, kinetic studies, NMR spectra (¹H NMR, ¹³C NMR, ²⁹Si NMR, and ¹¹B NMR), mass spectra, and Raman spectra (PDF) Correction to “Deoxygenation of 1° and 2° Amides with Ce[N(SiMe₃)₂]₃(THF)₃ under Mild Conditions” 4 views 0 shares 0 downloads Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html. This article has not yet been cited by other publications.