Core-sheath composite electric cables with highly conductive self-assembled carbon nanotube wires and flexible macroscale insulating polymers for lightweight, metal-free motors

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES
Ki-Hyun Ryu, Dongju Lee, Min Ji Kim, Ji Hong Park, Seok-In Lim, Seo Gyun Kim, Jun Yeon Hwang, Bon-Cheol Ku, Nam Dong Kim, Seung Min Kim, Dae-Yoon Kim
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Abstract

Recent advancements in the development of lightweight conductors through the self-assembly of nanomaterials at the macroscopic scale have garnered significant attention for electrical wiring applications where weight reduction is critical, such as in the automotive and aerospace industries. In this study, we successfully demonstrate a metal-free motor constructed with a core-sheath composite electric cable (CSCEC), utilizing continuous carbon nanotube (CNT) wires and flexible macroscale insulating polymers. The electrical performance of these metal-free motors is significantly enhanced by incorporating a lyotropic liquid crystal (LLC)-assisted surface texturing (LAST) process. This process enables individual CNT dispersion through surface protonation at the primary level, effectively removing metal catalyst particles while preserving the intrinsic one-dimensional (1D) nanostructures crucial to their physical properties. Combined with the low density of CSCEC, the substantial increase in electrical conductivity achieved through compact packing and uniaxial orientation allows the specific rotational velocity of the metal-free motors to be comparable to that of copper (Cu)-based electrical conductors at the same applied voltages. Finally, we successfully powered a scale model car using a metal-free motor made from high-performance CSCECs, underscoring their potential as a sustainable, lightweight alternative to conventional metal-based wiring, advancing next-generation energy systems, and contributing to CO2 emission reduction.

Graphical abstract

Boosting the electrical performance of self-assembled carbon nanotube wires through a lyotropic liquid crystal-assisted surface texturing process enables core-sheath composite electric cables toward lightweight, metal-free motor applications.

芯-护套复合电缆,采用高导电性自组装碳纳米管导线和柔性宏观绝缘聚合物,适用于轻量化、无金属电机
最近在宏观尺度上通过纳米材料的自组装开发轻质导体的进展引起了对汽车和航空航天工业等减轻重量至关重要的电线应用的极大关注。在这项研究中,我们成功地展示了一种由芯-护套复合电缆(CSCEC)构成的无金属电机,该电缆采用连续碳纳米管(CNT)导线和柔性宏观绝缘聚合物。这些无金属电机的电气性能通过结合溶致液晶(LLC)辅助表面纹理(LAST)工艺显着增强。该工艺使单个碳纳米管在初级水平上通过表面质子化分散,有效地去除金属催化剂颗粒,同时保留对其物理性质至关重要的固有一维(1D)纳米结构。再加上CSCEC的低密度,通过紧凑的封装和单轴定向,电导率大幅提高,使得在相同的施加电压下,无金属电机的特定旋转速度可以与铜基电导体相媲美。最后,我们成功地使用高性能cscec制造的无金属电机为比例模型汽车提供动力,强调了cscec作为传统金属布线的可持续、轻量化替代方案的潜力,推动了下一代能源系统的发展,并有助于减少二氧化碳排放。通过溶性液晶辅助表面变形工艺提高自组装碳纳米管导线的电性能,使芯-护套复合电缆朝着轻量化、无金属的电机应用方向发展。
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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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