{"title":"High-temperature oxidation and hot corrosion behavior of CoMoCrSi coating by APS and HVOF spraying","authors":"Zhiqiang Yang, Daoxin Liu, Yanjie Liu, Kai Zhou, Mengyao Li, Junnan Wu, Kaifa Fan, Xiaohua Zhang","doi":"10.1016/j.surfcoat.2025.132136","DOIUrl":null,"url":null,"abstract":"<div><div>High-temperature oxidation behavior and hot corrosion failure mechanism of CoMoCrSi coatings (T800) prepared by atmospheric plasma spraying (APS) and high-velocity oxy-fuel spraying (HVOF) were investigated. The HVOF-T800 coating exhibited superior oxidation resistance during the oxidation. In the hot corrosion, the APS-T800 coating developed an external layer of CoMoO<sub>4</sub> and an internal layer of CoCr<sub>2</sub>O<sub>4</sub>, ultimately leading to internal delamination failure. Nevertheless, the HVOF-T800 coating formed an outer layer of Cr<sub>2</sub>O<sub>3</sub>, an intermediate layer of CoCr<sub>2</sub>O<sub>4</sub>, and an inner blocking layer of SiO<sub>2</sub>, resulting in interfacial delamination failure as the final failure mode, exhibited greater resistance to hot corrosion medium intrusion.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"507 ","pages":"Article 132136"},"PeriodicalIF":5.3000,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface & Coatings Technology","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0257897225004104","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
引用次数: 0
Abstract
High-temperature oxidation behavior and hot corrosion failure mechanism of CoMoCrSi coatings (T800) prepared by atmospheric plasma spraying (APS) and high-velocity oxy-fuel spraying (HVOF) were investigated. The HVOF-T800 coating exhibited superior oxidation resistance during the oxidation. In the hot corrosion, the APS-T800 coating developed an external layer of CoMoO4 and an internal layer of CoCr2O4, ultimately leading to internal delamination failure. Nevertheless, the HVOF-T800 coating formed an outer layer of Cr2O3, an intermediate layer of CoCr2O4, and an inner blocking layer of SiO2, resulting in interfacial delamination failure as the final failure mode, exhibited greater resistance to hot corrosion medium intrusion.
期刊介绍:
Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance:
A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting.
B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.