A cellulose based fluorescent microsphere for sensitive detection and efficient removal of hydrazine and its versatile applications in environmental samples and live plants

IF 12.2 1区环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL

Journal of Hazardous Materials Pub Date : 2025-04-11 DOI:10.1016/j.jhazmat.2025.138253

Zhiyuan Meng, Xinyan Li, Qian Ye, Shuo Zhang, Xu Xu, Yiqin Yang, Zhonglong Wang, Shifa Wang

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引用次数: 0

Abstract

Hydrazine (N₂H₄) is being extensively utilized in various industrial fields, yet its high toxicity can cause enormous adverse effects on human health and the ecological environment. Herein, an aggregation-induced emission (AIE) fluorescent probe FNA-B-CA (naphthalimide small molecule (FNA-B) grafting onto cellulose acetate (CA)) for sensitive detection and high effective removal of N₂H₄ was synthesized. Probe FNA-B-CA can recognize N₂H₄ across a wide pH range (5−12) with a low detection limit (84 nM), high selectivity, and strong anti-interference ability. It enabled quantitative detection of N₂H₄ concentrations in actual water and soil samples quantitatively and functioned as an efficient tool for tracking N₂H₄ in plant tissue (bean sprouts). More importantly, probe FNA-B-CA was hereby successfully prepared into fluorescent microspheres using the favorable processing properties of CA, further facilitating the simultaneous detection and adsorption of N₂H₄ in aqueous solutions.

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来源期刊

Journal of Hazardous Materials 工程技术-工程：环境

CiteScore

25.40

自引率

5.90%

发文量

3059

审稿时长

58 days

期刊介绍： The Journal of Hazardous Materials serves as a global platform for promoting cutting-edge research in the field of Environmental Science and Engineering. Our publication features a wide range of articles, including full-length research papers, review articles, and perspectives, with the aim of enhancing our understanding of the dangers and risks associated with various materials concerning public health and the environment. It is important to note that the term "environmental contaminants" refers specifically to substances that pose hazardous effects through contamination, while excluding those that do not have such impacts on the environment or human health. Moreover, we emphasize the distinction between wastes and hazardous materials in order to provide further clarity on the scope of the journal. We have a keen interest in exploring specific compounds and microbial agents that have adverse effects on the environment.