Assessment of mechanical traits and corrosion resistance in ZrC nanoceramic–strengthened Ni-W-P nanocomposite coatings

IF 2.6 4区 化学 Q3 ELECTROCHEMISTRY
Yi Sun, Shijun Xu, Jiamin Zhong, Yi He, Shihong Zhang, Han Liu, Qing Yuan, Xiangshan Hou, Quangang Chen, Zhiyuan Li
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Abstract

The electroless plating method was used in this work to successfully create a Ni-W-P/ZrC composite coating on an N80 carbon steel substrate. How the ceramic nanomaterial ZrC affected the coating’s mechanical property, surface morphology, and corrosion resistance has also been investigated in this work. The outcomes demonstrated that the addition of ZrC material can greatly enhance the performance of the coating in a severe environment. The coating’s surface flaws improve, its surface gets denser and more complete, and its grain size gets much more refined as the concentration of ZrC increases. This is particularly evident when the ZrC concentration is 4 g/L. Because of ZrC’s dispersion strengthening and grain refinement effects, the composite coating with 4 g/L of ZrC has an average friction coefficient of 0.524 in the friction test which is lower than the Ni-W-P alloy coating. It also has a narrower wear section and a significantly smaller wear volume (0.0011 mm3). Furthermore, ZrC significantly increases the composite coatings’ resistance to corrosion. The corrosion current density of the composite coating is 5.27 µA/cm2, the corrosion potential is − 0.282 V, and the impedance is 8.21 × 104 Ω⋅cm2 when the concentration of ZrC is 4 g/L.

ZrC纳米陶瓷增强Ni-W-P纳米复合涂层力学性能及耐蚀性能评价
采用化学镀方法在N80碳钢基体上成功制备了Ni-W-P/ZrC复合镀层。本文还研究了陶瓷纳米材料ZrC对涂层力学性能、表面形貌和耐腐蚀性的影响。结果表明,ZrC材料的加入可以大大提高涂层在恶劣环境下的性能。随着ZrC浓度的增加,涂层表面缺陷改善,表面致密完整,晶粒尺寸细化。当ZrC浓度为4 g/L时,这一点尤为明显。由于ZrC的弥散强化和晶粒细化作用,添加4 g/L ZrC的复合涂层在摩擦试验中的平均摩擦系数为0.524,低于Ni-W-P合金涂层。它还具有更窄的磨损部分和显着更小的磨损体积(0.0011 mm3)。此外,ZrC显著提高了复合涂层的耐腐蚀性能。当ZrC浓度为4 g/L时,复合镀层的腐蚀电流密度为5.27µA/cm2,腐蚀电位为−0.282 V,阻抗为8.21 × 104 Ω⋅cm2。
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来源期刊
CiteScore
4.80
自引率
4.00%
发文量
227
审稿时长
4.1 months
期刊介绍: The Journal of Solid State Electrochemistry is devoted to all aspects of solid-state chemistry and solid-state physics in electrochemistry. The Journal of Solid State Electrochemistry publishes papers on all aspects of electrochemistry of solid compounds, including experimental and theoretical, basic and applied work. It equally publishes papers on the thermodynamics and kinetics of electrochemical reactions if at least one actively participating phase is solid. Also of interest are articles on the transport of ions and electrons in solids whenever these processes are relevant to electrochemical reactions and on the use of solid-state electrochemical reactions in the analysis of solids and their surfaces. The journal covers solid-state electrochemistry and focusses on the following fields: mechanisms of solid-state electrochemical reactions, semiconductor electrochemistry, electrochemical batteries, accumulators and fuel cells, electrochemical mineral leaching, galvanic metal plating, electrochemical potential memory devices, solid-state electrochemical sensors, ion and electron transport in solid materials and polymers, electrocatalysis, photoelectrochemistry, corrosion of solid materials, solid-state electroanalysis, electrochemical machining of materials, electrochromism and electrochromic devices, new electrochemical solid-state synthesis. The Journal of Solid State Electrochemistry makes the professional in research and industry aware of this swift progress and its importance for future developments and success in the above-mentioned fields.
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