Spin-State Modulation by Host−Guest Chemistry with Cucurbiturils

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-11 DOI:10.1039/d5cc00979k

Ke Lu, Yu-Xiao Chen, Jie-Sheng Hu, Zhi-Kun Liu, Xin-Li Shi, Meng Yu, Alyona A. Starikova, Jun Tao

引用次数: 0

Abstract

The host-guest binding of Cucurbit[7]uril to a methylpyridinium-functionalized Co(II)-terpyridine complex shifts the spin equilibrium to the low-spin state (ΔT1/2 = 77 K) via secondary coordination sphere perturbation, providing new insights into tuning spin-crossover behaviors.

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利用葫芦素进行主-客体化学自旋态调制

Cucurbit[7]uril与甲基吡啶功能化Co(II)-三吡啶配合物的主客体结合通过二次配位球扰动将自旋平衡转移到低自旋态（ΔT1/2 = 77 K），为自旋交叉行为的调节提供了新的见解。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.