Chiral nanographenes exhibiting circularly polarized luminescence

Abstract

Chiral nanographenes constitute an unconventional material class that deviates from planar graphene cutouts. They have gained considerable attention for their ability to exhibit circularly polarized luminescence (CPL), which offers new opportunities in chiral optoelectronics. Their unique π-conjugated architectures, coupled with the ability to introduce chirality at the molecular level, have made them powerful contenders in developing next-generation optoelectronic devices. This review thoroughly explores recent advances in the synthesis, structural design, and CPL performance of chiral nanographenes. We delve into diverse strategies for inducing chirality, including covalent functionalization, helically twisted frameworks, and heteroatom doping, each of which unlocks distinct CPL behaviors. In addition, we discuss the mechanistic principles governing CPL and future directions in chiral nanographenes to achieve high dissymmetry factors (g_lum) and tunable emission properties. We also discuss the key challenges in this evolving field, including designing robust chiral frameworks, optimizing CPL efficiency, and scaling up real-world applications. Through this review, we aim to shed light on recent developments in the bottom-up synthesis of structurally precise chiral nanographenes and evaluate their impact on the growing domain of circularly polarized luminescent materials.