Zinc and Cadmium Remediation in Contaminated Soil by CaCO3-Biochar Material from Sugar Beet Industry

IF 3.8 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES
Roger Borges, Matheus B. Soares, Mariana P. Pollo, Luís Reynaldo F. Alleoni, Amanda S. Giroto, Maraisa Gonçalves, Michael Müller, Nicolai D. Jablonowski, Caue Ribeiro
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Abstract

Ore mining and other industrial processes can release toxic elements such as zinc and cadmium into the soil, posing a potential environmental risk. Biochar produced by biomass pyrolysis is proposed to treat contaminated soils by sorption of the contaminants while boosting soil fertility, water retention, and microbial activity. Here, we propose the utilization of Carbokalk, an inexpensive byproduct (spent lime, SL) of the sugar-beet industry, as an ideal source for soil-treatment biochar. We examined the pyrolysis of SL containing up to 20% organic matter at various temperatures and in an oxidizing (air) and inert (N2) atmosphere. Our results indicate that the pyrolysis temperatures and gas atmospheres greatly influence the physicochemical features of SL-biochar, identifying the most suitable temperature of 600 ºC for both atmospheres. SL-biochar incubation in contaminated soil has shown the potential to mitigate metal contamination in soils. However, under an oxidizing atmosphere, SL-biochar provides higher reductions in exchangeable Zn and Cd fractions. It accounts for 3% and 20%, respectively, along with increases in fractions associated with carbonate and organic matter. These findings demonstrate the effectiveness of SL-biochar in immobilizing these contaminants.

利用甜菜业产生的 CaCO3 生物炭材料修复受污染土壤中的锌和镉
矿石开采和其他工业过程会将锌和镉等有毒元素释放到土壤中,构成潜在的环境风险。生物质热解产生的生物炭通过吸附污染物来处理污染土壤,同时提高土壤肥力、保水能力和微生物活性。在这里,我们提出利用糖甜菜工业的一种廉价的副产品(废石灰,SL)作为土壤处理生物炭的理想来源。我们研究了在不同温度下,在氧化(空气)和惰性(N2)气氛下,含有高达20%有机物的SL的热解。研究结果表明,热解温度和气体气氛对sl -生物炭的理化特性影响较大,确定了600℃的热解温度和气体气氛对sl -生物炭的最适宜温度。sl -生物炭在污染土壤中培养已显示出减轻土壤中金属污染的潜力。然而,在氧化气氛下,sl -生物炭提供了更高的交换性Zn和Cd组分的还原。它分别占3%和20%,同时与碳酸盐和有机质相关的馏分也有所增加。这些发现证明了sl -生物炭在固定化这些污染物方面的有效性。
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来源期刊
Water, Air, & Soil Pollution
Water, Air, & Soil Pollution 环境科学-环境科学
CiteScore
4.50
自引率
6.90%
发文量
448
审稿时长
2.6 months
期刊介绍: Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments. Articles should not be submitted that are of local interest only and do not advance international knowledge in environmental pollution and solutions to pollution. Articles that simply replicate known knowledge or techniques while researching a local pollution problem will normally be rejected without review. Submitted articles must have up-to-date references, employ the correct experimental replication and statistical analysis, where needed and contain a significant contribution to new knowledge. The publishing and editorial team sincerely appreciate your cooperation. Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.
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