Smartphone Sensing Platform Based on CdTe-Al3+ Quantum Dots Fluorescent Nanosensor for Visual Detection of Norfloxacin in Real Samples.

IF 2.6 4区 化学 Q2 BIOCHEMICAL RESEARCH METHODS
Ziqing Ye, Kedian Xu, Yunling Gao
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引用次数: 0

Abstract

A rapid and sensitive ratiometric fluorescence nanosensor for the detection of norfloxacin was obtained, where the yellow-emitting CdTe quantum dots (QDs) were as an internal reference and aluminium ion (Al³⁺) chelated on the QDs surface as the sensing unit. The nanosensor was characterized by transmission electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. As the concentration of norfloxacin increased, the sensor exhibited a continuous fluorescence color transition from yellow to blue. The CdTe-Al³⁺ QDs sensor demonstrated a low limit of detection of 6.6 nM. The ratiometric fluorescence sensor was also integrated with a smartphone color recognizer for visual and quantitative detection of norfloxacin with a limit of detection of 1.57 µM. This sensing platform exhibits excellent sensitivity, selectivity, and anti-interference performance, and it has great potential for on-site and quantitative analysis.

基于CdTe-Al3+量子点荧光纳米传感器的智能手机传感平台用于实际样品中诺氟沙星的视觉检测。
以黄色发光的CdTe量子点(QDs)为内参,在量子点表面螯合的铝离子(Al³+)为传感单元,制备了一种用于诺氟沙星检测的快速、灵敏的比例荧光纳米传感器。采用透射电子显微镜、傅里叶变换红外光谱和x射线光电子能谱对纳米传感器进行了表征。随着诺氟沙星浓度的增加,传感器呈现出从黄色到蓝色的连续荧光颜色转变。CdTe-Al³⁺QDs传感器的检测下限为6.6 nM。该比例荧光传感器还集成了智能手机颜色识别器,用于诺氟沙星的视觉和定量检测,检测限为1.57µM。该传感平台具有良好的灵敏度、选择性和抗干扰性能,在现场和定量分析方面具有很大的潜力。
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来源期刊
Journal of Fluorescence
Journal of Fluorescence 化学-分析化学
CiteScore
4.60
自引率
7.40%
发文量
203
审稿时长
5.4 months
期刊介绍: Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.
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