Inside Front Cover: High-Performance Overall Water Splitting Dominated by Direct Ligand-to-Cluster Photoexcitation in Metal−Organic Frameworks (Angew. Chem. 15/2025)
Qia-Chun Lin, Wei-Ming Liao, Jiayu Li, Bowei Ye, Da-Tang Chen, Xiao-Xiang Zhou, Peng-Hui Li, Meng Li, Ming-De Li, Jun He
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引用次数: 0
Abstract
In their Research Article (e202423070), Jun He, Wei-Ming Liao et al. report the construction of metal-organic frameworks (MOFs) using carbazole linker and trinuclear clusters, which facilitate photoinduced ligand-to-cluster charge transfer (LCCT). The study reveals that the photocatalytic performance for overall water splitting (OWS) via a direct LCCT pathway surpassed that of an indirect LCCT pathway. The direct LCCT mechanism is pivotal in maximizing photon utilization efficiency and ensuring broad-spectrum OWS.
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