Evaluation of Electropolymerization as a Versatile Approach for Applying Conformal Polymer Electrolyte Films on Complex Micro-Scale Silicon Architectures
Yuyang Hou, Fiona Yu, Thomas Rüther, Theo Rodopoulos
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引用次数: 0
Abstract
Application of conformal thin polymer electrolyte coatings on architecturally complex conductive electrode surfaces in various microdevices presents a significant technical challenge using conventional thin-film deposition techniques. In this study, electro-grafting combined with electropolymerization is investigated as a more versatile technique for applying these electrolyte coatings in order to advance the development of 3D microbatteries. Gel polymer electrolyte (GPE) films of several micrometers of thickness are electrochemically polymerized on cylindrical silicon micropillars employed as the anode in a lithium-ion battery. This in-situ electrochemical method allowed greater control of polymer film formation by applying a suitably negative potential for a designated duration. Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy is used to analyze the surface and cross sections of polymer-coated silicon micropillars to evaluate film formation as a function of applied potential and electrodeposition time. Discrete robust GPE samples, with the same composition as those prepared by electropolymerization, are also prepared to simplify characterization. The polymer electrolyte exhibits good thermal and electrochemical stability, high discharge capacity, and excellent capacity retention at high rates when evaluated in a coin cell. These results suggest that the electrochemical electrolyte coating technique holds promise for fabricating small-scale lithium-ion batteries with complex electrode architectures.
期刊介绍:
Advanced Materials Interfaces publishes top-level research on interface technologies and effects. Considering any interface formed between solids, liquids, and gases, the journal ensures an interdisciplinary blend of physics, chemistry, materials science, and life sciences. Advanced Materials Interfaces was launched in 2014 and received an Impact Factor of 4.834 in 2018.
The scope of Advanced Materials Interfaces is dedicated to interfaces and surfaces that play an essential role in virtually all materials and devices. Physics, chemistry, materials science and life sciences blend to encourage new, cross-pollinating ideas, which will drive forward our understanding of the processes at the interface.
Advanced Materials Interfaces covers all topics in interface-related research:
Oil / water separation,
Applications of nanostructured materials,
2D materials and heterostructures,
Surfaces and interfaces in organic electronic devices,
Catalysis and membranes,
Self-assembly and nanopatterned surfaces,
Composite and coating materials,
Biointerfaces for technical and medical applications.
Advanced Materials Interfaces provides a forum for topics on surface and interface science with a wide choice of formats: Reviews, Full Papers, and Communications, as well as Progress Reports and Research News.