Evaluation of Electropolymerization as a Versatile Approach for Applying Conformal Polymer Electrolyte Films on Complex Micro-Scale Silicon Architectures

IF 4.3 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Yuyang Hou, Fiona Yu, Thomas Rüther, Theo Rodopoulos
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Abstract

Application of conformal thin polymer electrolyte coatings on architecturally complex conductive electrode surfaces in various microdevices presents a significant technical challenge using conventional thin-film deposition techniques. In this study, electro-grafting combined with electropolymerization is investigated as a more versatile technique for applying these electrolyte coatings in order to advance the development of 3D microbatteries. Gel polymer electrolyte (GPE) films of several micrometers of thickness are electrochemically polymerized on cylindrical silicon micropillars employed as the anode in a lithium-ion battery. This in-situ electrochemical method allowed greater control of polymer film formation by applying a suitably negative potential for a designated duration. Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy is used to analyze the surface and cross sections of polymer-coated silicon micropillars to evaluate film formation as a function of applied potential and electrodeposition time. Discrete robust GPE samples, with the same composition as those prepared by electropolymerization, are also prepared to simplify characterization. The polymer electrolyte exhibits good thermal and electrochemical stability, high discharge capacity, and excellent capacity retention at high rates when evaluated in a coin cell. These results suggest that the electrochemical electrolyte coating technique holds promise for fabricating small-scale lithium-ion batteries with complex electrode architectures.

Abstract Image

评价电聚合作为一种将共形聚合物电解质膜应用于复杂微尺度硅结构的通用方法
在各种微器件的结构复杂的导电电极表面上应用保形薄聚合物电解质涂层是传统薄膜沉积技术的一个重大技术挑战。在这项研究中,电接枝结合电聚合作为一种更通用的技术来应用这些电解质涂层,以推进3D微电池的发展。在锂离子电池的正极硅柱上电化学聚合了几微米厚的凝胶聚合物电解质(GPE)薄膜。这种原位电化学方法通过在指定的时间内施加适当的负电位,可以更好地控制聚合物薄膜的形成。利用扫描电子显微镜和能量色散x射线能谱分析了聚合物包覆硅微柱的表面和横截面,以评价薄膜形成作为施加电位和电沉积时间的函数。离散稳健的GPE样品,与那些通过电聚合制备相同的组成,也准备简化表征。聚合物电解质在硬币电池中表现出良好的热稳定性和电化学稳定性,高放电容量,以及在高速率下的优异容量保持。这些结果表明,电化学电解质涂层技术有望制造具有复杂电极结构的小型锂离子电池。
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来源期刊
Advanced Materials Interfaces
Advanced Materials Interfaces CHEMISTRY, MULTIDISCIPLINARY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.40
自引率
5.60%
发文量
1174
审稿时长
1.3 months
期刊介绍: Advanced Materials Interfaces publishes top-level research on interface technologies and effects. Considering any interface formed between solids, liquids, and gases, the journal ensures an interdisciplinary blend of physics, chemistry, materials science, and life sciences. Advanced Materials Interfaces was launched in 2014 and received an Impact Factor of 4.834 in 2018. The scope of Advanced Materials Interfaces is dedicated to interfaces and surfaces that play an essential role in virtually all materials and devices. Physics, chemistry, materials science and life sciences blend to encourage new, cross-pollinating ideas, which will drive forward our understanding of the processes at the interface. Advanced Materials Interfaces covers all topics in interface-related research: Oil / water separation, Applications of nanostructured materials, 2D materials and heterostructures, Surfaces and interfaces in organic electronic devices, Catalysis and membranes, Self-assembly and nanopatterned surfaces, Composite and coating materials, Biointerfaces for technical and medical applications. Advanced Materials Interfaces provides a forum for topics on surface and interface science with a wide choice of formats: Reviews, Full Papers, and Communications, as well as Progress Reports and Research News.
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