Synthetic reactions using a 3-D printed acid-catalyst

IF 2.1 3区化学 Q2 CHEMISTRY, ORGANIC

Tetrahedron Pub Date : 2025-04-03 DOI:10.1016/j.tet.2025.134636

Jacob C. Hood , Niechen Chen , Douglas A. Klumpp

引用次数: 0

Abstract

A 3-D printed cartridge was fabricated using acrylonitrile-butadiene-styrene (ABS) printer filament. The cartridge was printed with an internal helical honeycomb channel pattern - providing a high surface area suitable for flow chemistry. The internal chamber of the cartridge was treated with fuming sulfuric acid to anneal the surface and functionalize the material with sulfonic acid groups. The 3-D printed catalyst was then used in a variety acid-catalyzed organic reactions, with conversions in 52–97 % yields.

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使用 3-D 打印酸催化剂进行合成反应

使用丙烯腈-丁二烯-苯乙烯（ABS）打印机长丝制作了一个 3-D 打印墨盒。筒体内部印有螺旋蜂窝状通道图案--提供了适合流动化学的高表面积。墨盒的内腔用发烟硫酸处理，使表面退火，并用磺酸基团使材料功能化。然后将这种 3-D 打印催化剂用于各种酸催化有机反应，转化率为 52-97 %。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Tetrahedron 化学-有机化学

CiteScore

3.90

自引率

4.80%

发文量

439

审稿时长

34 days

期刊介绍： Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.