Fe³⁺-mediated selective 1,2-Se (S) bifunctionalization of olefin.

IF 2.9 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2025-04-04 DOI:10.1039/d5ob00248f

Hong Yang, Gao-Wen Ren, Zhang-Gao Le, Zong-Bo Xie

引用次数: 0

Abstract

A one-pot, four-component reaction for simultaneously constructing C-Se, C-S, and C-N bonds via iron-mediated olefin 1,2-bifunctionalization was described. β-Selenylethyl dithiocarbamates were obtained highly efficiently with a wide substrate scope and remarkable regioselectivity. Notably, non-activated olefins exhibit higher reactivity in this reaction system, achieving yields of up to 99%.

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该研究描述了一种通过铁介导的烯烃 1,2 双官能化同时构建 C-Se、C-S 和 C-N 键的一锅四组分反应。β-硒乙基二硫代氨基甲酸酯的获得效率高、底物范围广且具有显著的区域选择性。值得注意的是，非活化烯烃在该反应体系中表现出更高的反应活性，产率高达 99%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.

Fe3+-mediated selective 1,2-Se (S) bifunctionalization of olefin.

Abstract

Fe³⁺-mediated selective 1,2-Se (S) bifunctionalization of olefin.