Hydrogen production technologies from water decomposition: A review

Wu Zhou , Shuangjiang Li , Yang Yang , Jiachao Yao , Pengfei Chen , Jian Liu , Yang Wu , Zhi Li , Fangming Jin
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Abstract

Hydrogen is a promising energy carrier in the future, which can help improve air quality and enhance energy security. Hydrogen production mainly relies on fossil fuels (natural gas and coal). Hydrogen production from fossil fuels can result in the significant emissions of carbon dioxide, aggravating the global greenhouse effect. At the same time, fossil fuels are non-renewable, and the use of fossil fuels to produce hydrogen further exacerbates the crisis of fossil fuel shortages. Fortunately, water, as a carbon-free and hydrogen-rich renewable resource, offers one of the best solutions to replace hydrogen production from fossil fuels through its decomposition. Furthermore, hydrogen production by decomposition of water is vital for the realization of the sustainable development. In this paper, we review the current mainstream technologies (electrolysis, pyrolysis and photolysis) for hydrogen production by decomposing water. The principles, processes, advantages and disadvantages and the latest progresses of these technologies are also discussed. At last, this paper provides a summary and outlook on water decomposition for hydrogen production, and thinks that the yield, energy efficiency and cost of hydrogen production from water decomposition are largely dependent on the development of new materials and the improvement of existing materials. Moreover, utilizing renewable energy to decompose water for hydrogen production offers the possibility of achieving the hydrogen economy.

Abstract Image

水分解制氢技术综述
氢是未来很有前途的能源载体,可以帮助改善空气质量,增强能源安全。氢气生产主要依赖于化石燃料(天然气和煤)。化石燃料制氢会导致大量二氧化碳排放,加剧全球温室效应。同时,化石燃料是不可再生的,利用化石燃料制氢进一步加剧了化石燃料短缺的危机。幸运的是,水作为一种无碳和富氢的可再生资源,通过其分解提供了替代化石燃料制氢的最佳解决方案之一。此外,水的分解制氢对实现可持续发展至关重要。本文综述了目前主流的水分解制氢技术(电解、热解和光解)。讨论了这些技术的原理、工艺、优缺点及最新进展。最后,对水分解制氢的研究进行了总结和展望,认为水分解制氢的产率、能源效率和成本在很大程度上取决于新材料的开发和现有材料的改进。此外,利用可再生能源分解水用于制氢,为实现氢经济提供了可能。
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