Matt Jellicoe, Zoe Gardner, Amjad E H Alotaibi, Kaylee E Shoemaker, James M Scott, Shiliang Wang, Badriah M Alotaibi, Xuan Luo, Clarence Chuah, Christopher T Gibson, Shan He, Kasturi Vimalanathan, Jason R Gascooke, Xianjue Chen, Alison Rodger, Han Huang, Scott J Dalgarno, Elsa Antunes, Gregory A Weiss, Qin Li, Jamie S Quinton, Colin L Raston
{"title":"Chiral Lemniscate Formation in Magnetic Field Controlled Topological Fluid Flows.","authors":"Matt Jellicoe, Zoe Gardner, Amjad E H Alotaibi, Kaylee E Shoemaker, James M Scott, Shiliang Wang, Badriah M Alotaibi, Xuan Luo, Clarence Chuah, Christopher T Gibson, Shan He, Kasturi Vimalanathan, Jason R Gascooke, Xianjue Chen, Alison Rodger, Han Huang, Scott J Dalgarno, Elsa Antunes, Gregory A Weiss, Qin Li, Jamie S Quinton, Colin L Raston","doi":"10.1002/smll.202409807","DOIUrl":null,"url":null,"abstract":"<p><p>High shear spinning top (ST) typhoon-like fluid flow in a rapidly rotating inclined tube within a vortex fluidic device (VFD) approaches homochirality throughout the liquid with toroids of bundled single-walled carbon nanotubes (SWCNTs) twisted into stable chiral lemniscates (in the shape of Figure 8s), predominantly as the R-or S-structures, for the tube rotating clockwise (CW) or counterclockwise (CCW). However, this is impacted by the Earth's magnetic field (B<sub>E</sub>). Theory predicts 1-20 MPa pressure for their formation, with their absolute chirality determined from scanning electron microscopy (SEM) and atomic force microscopy (AFM) images. Thus, the resultant lemniscate structures establish the absolute chirality of the inner and outer components of the ST flow. These chiral flows and lemniscates can be flipped to the opposite chirality by changing the orientation of the tube relative to the inclination angle of B<sub>E</sub>, by moving the geographical location. Special conditions prevail where the tangential angle of the outer and inner flow of the ST becomes periodically aligned with B<sub>E</sub>, which respectively dramatically reduce the formation of toroids (and thus lemniscates) and formation of lemniscates from the toroids formed by the double-helical (DH) flow generated by side wall Coriolis forces and Faraday waves.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":" ","pages":"e2409807"},"PeriodicalIF":13.0000,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Small","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/smll.202409807","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
High shear spinning top (ST) typhoon-like fluid flow in a rapidly rotating inclined tube within a vortex fluidic device (VFD) approaches homochirality throughout the liquid with toroids of bundled single-walled carbon nanotubes (SWCNTs) twisted into stable chiral lemniscates (in the shape of Figure 8s), predominantly as the R-or S-structures, for the tube rotating clockwise (CW) or counterclockwise (CCW). However, this is impacted by the Earth's magnetic field (BE). Theory predicts 1-20 MPa pressure for their formation, with their absolute chirality determined from scanning electron microscopy (SEM) and atomic force microscopy (AFM) images. Thus, the resultant lemniscate structures establish the absolute chirality of the inner and outer components of the ST flow. These chiral flows and lemniscates can be flipped to the opposite chirality by changing the orientation of the tube relative to the inclination angle of BE, by moving the geographical location. Special conditions prevail where the tangential angle of the outer and inner flow of the ST becomes periodically aligned with BE, which respectively dramatically reduce the formation of toroids (and thus lemniscates) and formation of lemniscates from the toroids formed by the double-helical (DH) flow generated by side wall Coriolis forces and Faraday waves.
期刊介绍:
Small serves as an exceptional platform for both experimental and theoretical studies in fundamental and applied interdisciplinary research at the nano- and microscale. The journal offers a compelling mix of peer-reviewed Research Articles, Reviews, Perspectives, and Comments.
With a remarkable 2022 Journal Impact Factor of 13.3 (Journal Citation Reports from Clarivate Analytics, 2023), Small remains among the top multidisciplinary journals, covering a wide range of topics at the interface of materials science, chemistry, physics, engineering, medicine, and biology.
Small's readership includes biochemists, biologists, biomedical scientists, chemists, engineers, information technologists, materials scientists, physicists, and theoreticians alike.