Unveiling mechanistic insights and applications of aggregation-enhanced emission (AEE)-active polynuclear transition metal complexes.

Abstract

Aggregation-enhanced emission (AEE) in polynuclear transition metal complexes (PTMCs) represents a major advancement in luminescent materials, overcoming the limitations of aggregation-caused quenching (ACQ) in traditional systems. Unlike conventional materials that suffer from quenching, AEE-active PTMCs exhibit enhanced luminescence in the aggregated state, driven by mechanisms such as restricted molecular motion, π-π stacking, and metal-metal interactions. These properties make PTMCs highly versatile for applications including chemical sensing, bioimaging, photodynamic therapy (PDT), optoelectronics (e.g., OLEDs, WOLEDs, and LEDs), and security technologies (e.g., anti-counterfeiting inks). They enable the sensitive detection of pollutants, facilitate high-performance bioimaging, and enhance the efficiency of energy devices. However, PTMCs face several challenges, including complex synthesis, limited thermal and photostability, solubility issues, and environmental and toxicity concerns. Additionally, high production costs, instability in different media, and the need for optimized energy transfer efficiency must be addressed to enhance their practical performance. This review explores the mechanisms behind AEE in PTMCs and discusses strategies for overcoming these challenges, including ligand engineering, hybrid material development, and sustainable synthesis methods. It also highlights their potential in advancing energy-efficient technologies, precision therapeutics, and secure communication systems, contributing to a more sustainable and innovative future.