Facile preparation and properties of foamed fly-ash/slag-based hollow glass microspheres/geopolymer composites

IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS
Shu Yan, Chenyang He, Man Zhang, Wenguang Wang, Shengwei Wang
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Abstract

In order to reuse the multiple solid waste and improve the porosity of geopolymer composites, a unique foaming process was developed to fabricate novel green foamed fly-ash/slag-based hollow glass microspheres/geopolymer (HGMs/FSGP) composites. A thorough investigation was carried out on the synergic effects of cetyltrimethylammonium bromide (CTAB), hydrogen peroxide (H2O2) and HGMs on the microstructure, strength and thermal conductivity. Results showed that the foamed HGMs/FSGP composites with the amorphous structure could be fabricated by foaming combined with HGMs at room temperature. The density of the samples changed from 1.16 to 0.47 g/cm3 with 1–5 wt.% H2O2. The acceptable compressive strength (0.71–15.05 MPa) of the HGMs/FSGP composites was attributed to the fractured HGMs, the good bond between HGMs and geopolymer matrix, and crack deflection across the HGMs. With proper H2O2 and HGMs, the composites obtained their lowest thermal conductivity of 0.116 W/(m⋅K), which could find use in insulation fields.

泡沫粉煤灰/渣基中空玻璃微球/地聚合物复合材料的制备及性能研究
为了回收利用多种固体废弃物,提高地聚合物复合材料的孔隙率,采用独特的发泡工艺制备了新型绿色发泡粉煤灰/矿渣基中空玻璃微球/地聚合物(HGMs/FSGP)复合材料。研究了十六烷基三甲基溴化铵(CTAB)、过氧化氢(H2O2)和hgm对复合材料微观结构、强度和导热性能的协同效应。结果表明:室温下与HGMs复合发泡可制备出具有非晶结构的泡沫HGMs/FSGP复合材料。当H2O2浓度为1-5 wt.%时,样品的密度变化范围为1.16 ~ 0.47 g/cm3。hgm /FSGP复合材料具有良好的抗压强度(0.71-15.05 MPa),主要归因于hgm断裂、hgm与地聚合物基体的良好结合以及hgm间的裂纹挠度。在适当的H2O2和hgm条件下,复合材料的导热系数最低,为0.116 W/(m·K),可用于保温领域。
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来源期刊
International Journal of Applied Ceramic Technology
International Journal of Applied Ceramic Technology 工程技术-材料科学:硅酸盐
CiteScore
3.90
自引率
9.50%
发文量
280
审稿时长
4.5 months
期刊介绍: The International Journal of Applied Ceramic Technology publishes cutting edge applied research and development work focused on commercialization of engineered ceramics, products and processes. The publication also explores the barriers to commercialization, design and testing, environmental health issues, international standardization activities, databases, and cost models. Designed to get high quality information to end-users quickly, the peer process is led by an editorial board of experts from industry, government, and universities. Each issue focuses on a high-interest, high-impact topic plus includes a range of papers detailing applications of ceramics. Papers on all aspects of applied ceramics are welcome including those in the following areas: Nanotechnology applications; Ceramic Armor; Ceramic and Technology for Energy Applications (e.g., Fuel Cells, Batteries, Solar, Thermoelectric, and HT Superconductors); Ceramic Matrix Composites; Functional Materials; Thermal and Environmental Barrier Coatings; Bioceramic Applications; Green Manufacturing; Ceramic Processing; Glass Technology; Fiber optics; Ceramics in Environmental Applications; Ceramics in Electronic, Photonic and Magnetic Applications;
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