Investigation of the morphological change of stable copper nanoparticles synthesized in different concentrations of polyvinyl alcohol and its catalytic activities on dye degradation

IF 2.2 4区 化学 Q2 Engineering
Suman Mandal
{"title":"Investigation of the morphological change of stable copper nanoparticles synthesized in different concentrations of polyvinyl alcohol and its catalytic activities on dye degradation","authors":"Suman Mandal","doi":"10.1007/s11696-025-03909-9","DOIUrl":null,"url":null,"abstract":"<div><p>Studies on copper nanoparticles (CuNPs) synthesis and its applications have been published on the basis of using different methods and reactants to minimize difficulties related to the experiments. This work mainly focuses on the synthesis of size- and shape-controlled copper nanoparticles by using nontoxic chemicals, a simple and cost-effective method, and its application. For that purpose, polyvinyl alcohol (PVA) solutions of different concentrations had been prepared to control the shapes and sizes of synthesized CuNPs produced by the reduction method using L-ascorbic acid at optimized conditions. Unlike others, instead of PVA film or gel, here standard PVA aqueous solutions were used. The different natures of the particles synthesized at different concentrations of PVA were examined successfully. It had been revealed that high concentration of PVA helps to stabilize the CuNPs by forming a stable cage-like structure. Polycrystalline, pentagonal, cylindrical, and spherical CuNPs of average size (11 nm) were synthesized by controlling the concentration of PVA solution. Lone L-ascorbic acid is unable to do that. This is the novelty of this work. The data obtained from UV–vis spectroscopy, DLS, TEM, XRD and fluorescence analysis facilitates establishing the fact. Additionally, it has also been observed that the special sized and shaped CuNPs are very effective in methyl orange (MO) dye degradation catalysis.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 4","pages":"2105 - 2120"},"PeriodicalIF":2.2000,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Papers","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11696-025-03909-9","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Engineering","Score":null,"Total":0}
引用次数: 0

Abstract

Studies on copper nanoparticles (CuNPs) synthesis and its applications have been published on the basis of using different methods and reactants to minimize difficulties related to the experiments. This work mainly focuses on the synthesis of size- and shape-controlled copper nanoparticles by using nontoxic chemicals, a simple and cost-effective method, and its application. For that purpose, polyvinyl alcohol (PVA) solutions of different concentrations had been prepared to control the shapes and sizes of synthesized CuNPs produced by the reduction method using L-ascorbic acid at optimized conditions. Unlike others, instead of PVA film or gel, here standard PVA aqueous solutions were used. The different natures of the particles synthesized at different concentrations of PVA were examined successfully. It had been revealed that high concentration of PVA helps to stabilize the CuNPs by forming a stable cage-like structure. Polycrystalline, pentagonal, cylindrical, and spherical CuNPs of average size (11 nm) were synthesized by controlling the concentration of PVA solution. Lone L-ascorbic acid is unable to do that. This is the novelty of this work. The data obtained from UV–vis spectroscopy, DLS, TEM, XRD and fluorescence analysis facilitates establishing the fact. Additionally, it has also been observed that the special sized and shaped CuNPs are very effective in methyl orange (MO) dye degradation catalysis.

Abstract Image

研究了不同浓度聚乙烯醇合成的稳定铜纳米颗粒的形态变化及其对染料降解的催化活性
在使用不同的方法和反应物以尽量减少实验困难的基础上,对铜纳米颗粒(cu纳米粒子)的合成及其应用进行了研究。本文主要研究了利用无毒化学物质合成尺寸和形状可控的铜纳米粒子的方法及其应用。为此,制备了不同浓度的聚乙烯醇(PVA)溶液,以控制l -抗坏血酸还原法在最佳条件下合成的聚乙烯醇的形状和大小。与其他不同的是,这里使用的不是PVA薄膜或凝胶,而是标准的PVA水溶液。成功地考察了在不同PVA浓度下合成的颗粒的不同性质。研究表明,高浓度的PVA通过形成稳定的笼状结构有助于稳定CuNPs。通过控制聚乙烯醇溶液的浓度,合成了平均尺寸为11 nm的多晶、五边形、圆柱形和球形聚乙烯醇。抗坏血酸不能做到这一点。这是这项工作的新奇之处。紫外-可见光谱、DLS、TEM、XRD和荧光分析数据有助于确立这一事实。此外,还观察到特殊尺寸和形状的CuNPs在甲基橙(MO)染料降解中具有非常有效的催化作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Chemical Papers
Chemical Papers Chemical Engineering-General Chemical Engineering
CiteScore
3.30
自引率
4.50%
发文量
590
期刊介绍: Chemical Papers is a peer-reviewed, international journal devoted to basic and applied chemical research. It has a broad scope covering the chemical sciences, but favors interdisciplinary research and studies that bring chemistry together with other disciplines.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信