Enhanced cyclic compression performance of polyolefin elastomer foams with novel open-cell structures through mixed gases regulation

IF 3.4 3区 工程技术 Q2 CHEMISTRY, PHYSICAL
Daoen Yu, Shaozhe Shi, Fangfang Zou, Bo Wang, Guangxian Li, Xia Liao
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引用次数: 0

Abstract

Polyolefin elastomer (POE) foam with a novel open-cell structure, termed the island open-cell structure, was fabricated by melt blending two kinds of POE with distinct melting points, followed by foaming using a mixture of CO₂ and N₂ as blowing agents. The formation and evolution mechanisms of the unique open-cell structure were elucidated through gas solubility test and high-pressure rheology, focusing on cell nucleation and growth behaviors. A controlled transition from the island open-cell structure to semi-continuous and continuous open-cell structures was achieved through the optimized foaming process. The effect of different open-cell structures on the compressive performance of POE foams was investigated through cyclic compression tests. The result indicates that POE foam with the island open-cell structure exhibits the highest compressive strength among semi-continuous open-cell, continuous open-cell and closed-cell structures.
通过混合气体调节提高新型开孔结构聚烯烃弹性体泡沫的循环压缩性能
将两种熔点不同的聚烯烃弹性体(POE)熔融共混,然后以CO₂和N₂的混合物为发泡剂进行发泡,制备了具有新型开孔结构的聚烯烃弹性体(POE)泡沫,称为岛状开孔结构。通过气溶性实验和高压流变学研究了独特开孔结构的形成和演化机制,重点研究了细胞的成核和生长行为。通过优化发泡工艺,实现了由岛状开孔结构向半连续和连续开孔结构的可控过渡。通过循环压缩试验,研究了不同开孔结构对POE泡沫材料压缩性能的影响。结果表明:在半连续开孔、连续开孔和闭孔结构中,岛状开孔结构的POE泡沫具有最高的抗压强度;
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来源期刊
Journal of Supercritical Fluids
Journal of Supercritical Fluids 工程技术-工程:化工
CiteScore
7.60
自引率
10.30%
发文量
236
审稿时长
56 days
期刊介绍: The Journal of Supercritical Fluids is an international journal devoted to the fundamental and applied aspects of supercritical fluids and processes. Its aim is to provide a focused platform for academic and industrial researchers to report their findings and to have ready access to the advances in this rapidly growing field. Its coverage is multidisciplinary and includes both basic and applied topics. Thermodynamics and phase equilibria, reaction kinetics and rate processes, thermal and transport properties, and all topics related to processing such as separations (extraction, fractionation, purification, chromatography) nucleation and impregnation are within the scope. Accounts of specific engineering applications such as those encountered in food, fuel, natural products, minerals, pharmaceuticals and polymer industries are included. Topics related to high pressure equipment design, analytical techniques, sensors, and process control methodologies are also within the scope of the journal.
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