{"title":"Enhanced cyclic compression performance of polyolefin elastomer foams with novel open-cell structures through mixed gases regulation","authors":"Daoen Yu, Shaozhe Shi, Fangfang Zou, Bo Wang, Guangxian Li, Xia Liao","doi":"10.1016/j.supflu.2025.106617","DOIUrl":null,"url":null,"abstract":"<div><div>Polyolefin elastomer (POE) foam with a novel open-cell structure, termed the island open-cell structure, was fabricated by melt blending two kinds of POE with distinct melting points, followed by foaming using a mixture of CO₂ and N₂ as blowing agents. The formation and evolution mechanisms of the unique open-cell structure were elucidated through gas solubility test and high-pressure rheology, focusing on cell nucleation and growth behaviors. A controlled transition from the island open-cell structure to semi-continuous and continuous open-cell structures was achieved through the optimized foaming process. The effect of different open-cell structures on the compressive performance of POE foams was investigated through cyclic compression tests. The result indicates that POE foam with the island open-cell structure exhibits the highest compressive strength among semi-continuous open-cell, continuous open-cell and closed-cell structures.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"222 ","pages":"Article 106617"},"PeriodicalIF":3.4000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Supercritical Fluids","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0896844625001044","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Polyolefin elastomer (POE) foam with a novel open-cell structure, termed the island open-cell structure, was fabricated by melt blending two kinds of POE with distinct melting points, followed by foaming using a mixture of CO₂ and N₂ as blowing agents. The formation and evolution mechanisms of the unique open-cell structure were elucidated through gas solubility test and high-pressure rheology, focusing on cell nucleation and growth behaviors. A controlled transition from the island open-cell structure to semi-continuous and continuous open-cell structures was achieved through the optimized foaming process. The effect of different open-cell structures on the compressive performance of POE foams was investigated through cyclic compression tests. The result indicates that POE foam with the island open-cell structure exhibits the highest compressive strength among semi-continuous open-cell, continuous open-cell and closed-cell structures.
期刊介绍:
The Journal of Supercritical Fluids is an international journal devoted to the fundamental and applied aspects of supercritical fluids and processes. Its aim is to provide a focused platform for academic and industrial researchers to report their findings and to have ready access to the advances in this rapidly growing field. Its coverage is multidisciplinary and includes both basic and applied topics.
Thermodynamics and phase equilibria, reaction kinetics and rate processes, thermal and transport properties, and all topics related to processing such as separations (extraction, fractionation, purification, chromatography) nucleation and impregnation are within the scope. Accounts of specific engineering applications such as those encountered in food, fuel, natural products, minerals, pharmaceuticals and polymer industries are included. Topics related to high pressure equipment design, analytical techniques, sensors, and process control methodologies are also within the scope of the journal.