MARVEL analysis of high-resolution rovibrational spectra of 16O12C17O

IF 2.3 3区物理与天体物理 Q2 OPTICS

Journal of Quantitative Spectroscopy & Radiative Transfer Pub Date : 2025-04-01 DOI:10.1016/j.jqsrt.2025.109444

Saja A.M. Obaidat , Ala’a A.A. Azzam , Dunia Alatoom , Mohammad Taha I. Ibrahim , Jonathan Tennyson , Tibor Furtenbacher , Attila G. Császár

{"title":"MARVEL analysis of high-resolution rovibrational spectra of 16O12C17O","authors":"Saja A.M. Obaidat , Ala’a A.A. Azzam , Dunia Alatoom , Mohammad Taha I. Ibrahim , Jonathan Tennyson , Tibor Furtenbacher , Attila G. Császár","doi":"10.1016/j.jqsrt.2025.109444","DOIUrl":null,"url":null,"abstract":"<div><div>16O12C17O is the fourth most abundant isotopologue of carbon dioxide. As part of this study, a total of 16223 rovibrational transitions, 9822 unique ones, measured for the ground electronic state of CO<math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math>, were collected from 31 articles, corresponding to the limited wavenumber range of 634–12727 cm−1. The measured transitions span the polyads <math><mrow><mi>P</mi><mo>=</mo><mn>0</mn><mo>−</mo><mn>17</mn></mrow></math>, where <math><mrow><mi>P</mi><mo>=</mo><mn>2</mn><msub><mrow><mi>v</mi></mrow><mrow><mn>1</mn></mrow></msub><mo>+</mo><msub><mrow><mi>v</mi></mrow><mrow><mn>2</mn></mrow></msub><mo>+</mo><mn>3</mn><msub><mrow><mi>v</mi></mrow><mrow><mn>3</mn></mrow></msub></mrow></math>, and <math><msub><mrow><mi>v</mi></mrow><mrow><mn>1</mn></mrow></msub></math>, <math><msub><mrow><mi>v</mi></mrow><mrow><mn>2</mn></mrow></msub></math>, and <math><msub><mrow><mi>v</mi></mrow><mrow><mn>3</mn></mrow></msub></math> are the normal-mode quantum numbers corresponding to the symmetric stretch, linear bend, and antisymmetric stretch motions. Following a careful validation of the compiled rovibrational transitions data, a set of 5036 empirical rovibrational energy levels has been determined. Comparison of the empirical energy-level data of this study with those in the CDSD-296 and NASA Ames-2021 line lists shows good general agreement.</div></div>","PeriodicalId":16935,"journal":{"name":"Journal of Quantitative Spectroscopy & Radiative Transfer","volume":"340 ","pages":"Article 109444"},"PeriodicalIF":2.3000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Quantitative Spectroscopy & Radiative Transfer","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022407325001062","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"OPTICS","Score":null,"Total":0}

引用次数: 0

Abstract

¹⁶O¹²C¹⁷O is the fourth most abundant isotopologue of carbon dioxide. As part of this study, a total of 16 223 rovibrational transitions, 9822 unique ones, measured for the ground electronic state of CO

_{2}

, were collected from 31 articles, corresponding to the limited wavenumber range of 634–12 727 cm⁻¹. The measured transitions span the polyads

P = 0 - 17

, where

P = 2 v_{1} + v_{2} + 3 v_{3}

, and

v_{1}

v_{2}

, and

v_{3}

are the normal-mode quantum numbers corresponding to the symmetric stretch, linear bend, and antisymmetric stretch motions. Following a careful validation of the compiled rovibrational transitions data, a set of 5036 empirical rovibrational energy levels has been determined. Comparison of the empirical energy-level data of this study with those in the CDSD-296 and NASA Ames-2021 line lists shows good general agreement.

Abstract Image

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Quantitative Spectroscopy & Radiative Transfer 物理-光谱学

CiteScore

5.30

自引率

21.70%

发文量

273

审稿时长

58 days

期刊介绍： Papers with the following subject areas are suitable for publication in the Journal of Quantitative Spectroscopy and Radiative Transfer: - Theoretical and experimental aspects of the spectra of atoms, molecules, ions, and plasmas. - Spectral lineshape studies including models and computational algorithms. - Atmospheric spectroscopy. - Theoretical and experimental aspects of light scattering. - Application of light scattering in particle characterization and remote sensing. - Application of light scattering in biological sciences and medicine. - Radiative transfer in absorbing, emitting, and scattering media. - Radiative transfer in stochastic media.