{"title":"Mid- to Late-Holocene branched GDGT-based air temperatures from a crater lake in Cameroon (Central Africa)","authors":"Guillemette Ménot , Salomé Ansanay-Alex , Valérie F. Schwab , Gilbert Todou , Olivier Séné , Jean-Michel Onana , Gerd Gleixner , Dirk Sachse , Yannick Garcin","doi":"10.1016/j.orggeochem.2025.104982","DOIUrl":null,"url":null,"abstract":"<div><div>African low-latitude regions tend to be underrepresented in global continental temperature reconstructions, limiting both our understanding and the reliability of predictions of past and future changes in temperature and precipitation in those parts of the world. The lack of continuous sedimentary archives and quantitative temperature proxies further complicates this issue, especially outside Eastern Africa. Here, we use data collected in Cameroon lakes to assess branched glycerol dialkyl glycerol tetraether (brGDGT)-based temperature proxies and examine potential confounding variables impacting temperature reconstructions. By analyzing GDGT distributions in soil watershed, water column, and surface sediment samples from a total of 11 Cameroon lakes, we could verify that the degree of methylation of brGDGTs (through the MBT′<sub>5Me</sub>) can serve as a reliable indicator for reconstructing mean annual air temperatures. Additionally, we could confirm that surface water conductivity represents a controlling factor for the brGDGT assemblage in surface sediments of crater lakes. Moreover, we provide the first reconstruction of Mid- to Late-Holocene GDGT-based air temperatures for a crater lake in Cameroon (Central Africa), revealing a temperature decrease of 2.5 °C over the last 7000 years, which agrees with recently published records for East Africa but exceeds current model predictions. These discrepancies highlight the need for additional studies to focus on this geographically underrepresented area.</div></div>","PeriodicalId":400,"journal":{"name":"Organic Geochemistry","volume":"204 ","pages":"Article 104982"},"PeriodicalIF":2.6000,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Geochemistry","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0146638025000555","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
引用次数: 0
Abstract
African low-latitude regions tend to be underrepresented in global continental temperature reconstructions, limiting both our understanding and the reliability of predictions of past and future changes in temperature and precipitation in those parts of the world. The lack of continuous sedimentary archives and quantitative temperature proxies further complicates this issue, especially outside Eastern Africa. Here, we use data collected in Cameroon lakes to assess branched glycerol dialkyl glycerol tetraether (brGDGT)-based temperature proxies and examine potential confounding variables impacting temperature reconstructions. By analyzing GDGT distributions in soil watershed, water column, and surface sediment samples from a total of 11 Cameroon lakes, we could verify that the degree of methylation of brGDGTs (through the MBT′5Me) can serve as a reliable indicator for reconstructing mean annual air temperatures. Additionally, we could confirm that surface water conductivity represents a controlling factor for the brGDGT assemblage in surface sediments of crater lakes. Moreover, we provide the first reconstruction of Mid- to Late-Holocene GDGT-based air temperatures for a crater lake in Cameroon (Central Africa), revealing a temperature decrease of 2.5 °C over the last 7000 years, which agrees with recently published records for East Africa but exceeds current model predictions. These discrepancies highlight the need for additional studies to focus on this geographically underrepresented area.
期刊介绍:
Organic Geochemistry serves as the only dedicated medium for the publication of peer-reviewed research on all phases of geochemistry in which organic compounds play a major role. The Editors welcome contributions covering a wide spectrum of subjects in the geosciences broadly based on organic chemistry (including molecular and isotopic geochemistry), and involving geology, biogeochemistry, environmental geochemistry, chemical oceanography and hydrology.
The scope of the journal includes research involving petroleum (including natural gas), coal, organic matter in the aqueous environment and recent sediments, organic-rich rocks and soils and the role of organics in the geochemical cycling of the elements.
Sedimentological, paleontological and organic petrographic studies will also be considered for publication, provided that they are geochemically oriented. Papers cover the full range of research activities in organic geochemistry, and include comprehensive review articles, technical communications, discussion/reply correspondence and short technical notes. Peer-reviews organised through three Chief Editors and a staff of Associate Editors, are conducted by well known, respected scientists from academia, government and industry. The journal also publishes reviews of books, announcements of important conferences and meetings and other matters of direct interest to the organic geochemical community.