{"title":"Self-Aggregation Control of Porphyrin for Enhanced Selective Covalent Organic Network Membranes (Small 13/2025)","authors":"Zheng Wang, Keizo Nakagawa, Kecheng Guan, Mengyang Hu, Zhaohuan Mai, Wenming Fu, Qin Shen, Yasunao Okamoto, Atsushi Matsuoka, Eiji Kamio, Tomohisa Yoshioka, Hideto Matsuyama","doi":"10.1002/smll.202570102","DOIUrl":null,"url":null,"abstract":"<p><b>Covalent Organic Networks</b></p><p>In article number 2407986, Keizo Nakagawa, Hideto Matsuyama, and co-workers present porphyrin-based polyamide covalent organic networks with ordered structures through interfacial polymerization with acyl chlorides. By controlling the self-aggregation behavior of porphyrins and the conformation of acylchlorides, covalent networks with tailored pores (0.48–0.78 nm) was formed to achieve molecular separation in solvent governed by the size-sieving effect.\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":228,"journal":{"name":"Small","volume":"21 13","pages":""},"PeriodicalIF":13.0000,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/smll.202570102","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Small","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/smll.202570102","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Covalent Organic Networks
In article number 2407986, Keizo Nakagawa, Hideto Matsuyama, and co-workers present porphyrin-based polyamide covalent organic networks with ordered structures through interfacial polymerization with acyl chlorides. By controlling the self-aggregation behavior of porphyrins and the conformation of acylchlorides, covalent networks with tailored pores (0.48–0.78 nm) was formed to achieve molecular separation in solvent governed by the size-sieving effect.
期刊介绍:
Small serves as an exceptional platform for both experimental and theoretical studies in fundamental and applied interdisciplinary research at the nano- and microscale. The journal offers a compelling mix of peer-reviewed Research Articles, Reviews, Perspectives, and Comments.
With a remarkable 2022 Journal Impact Factor of 13.3 (Journal Citation Reports from Clarivate Analytics, 2023), Small remains among the top multidisciplinary journals, covering a wide range of topics at the interface of materials science, chemistry, physics, engineering, medicine, and biology.
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