Back Cover Image, Volume 7, Number 3, March 2025

IF 19.5 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Carbon Energy Pub Date : 2025-04-02 DOI:10.1002/cey2.70022

Binglan Wu, Karim Harrath, Marshet Getaye Sendeku, Tofik Ahmed Shifa, Yuxin Huang, Jing Tai, Fekadu Tsegaye Dajan, Kassa Belay Ibrahim, Xueying Zhan, Zhenxing Wang, Elisa Moretti, Ying Yang, Fengmei Wang, Alberto Vomiero

{"title":"Back Cover Image, Volume 7, Number 3, March 2025","authors":"Binglan Wu, Karim Harrath, Marshet Getaye Sendeku, Tofik Ahmed Shifa, Yuxin Huang, Jing Tai, Fekadu Tsegaye Dajan, Kassa Belay Ibrahim, Xueying Zhan, Zhenxing Wang, Elisa Moretti, Ying Yang, Fengmei Wang, Alberto Vomiero","doi":"10.1002/cey2.70022","DOIUrl":null,"url":null,"abstract":"<p><b><i>Back cover image</i></b>: Electrocatalytic selective oxidation of amines to imines is an attractive way to produce nitrile compounds, but it is limited by inefficient catalysts. Herein, we apply a oxyhydroxide layer formed on top of iron-doped layered nickel phosphorus trisulphides (Ni1-xFexPS3) to induce oxidation of benzylamine (BA). Structural and surface chemical characterizations during the electrocatalytic process combined with calculations reveal that Ni1-xFexPS3 undergoes surface reconstruction under alkaline conditions to form metal oxyhydroxide/phosphorus trichalcogenide (NiFeOOH/Ni1-xFexPS3) heterostructure. The heterointerface facilitates BA oxidation with a low onset potential of 1.39 V and Faradaic efficiency of 53% for benzonitrile synthesis. The NiFeOOH/Ni1-xFexPS3 heterostructure off ers optimum free energy for BA adsorption and benzonitrile desorption, resulting in promising benzonitrile synthesis. In article cey2.672, Wu et al.\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":33706,"journal":{"name":"Carbon Energy","volume":"7 3","pages":""},"PeriodicalIF":19.5000,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cey2.70022","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon Energy","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cey2.70022","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

Abstract

Back cover image: Electrocatalytic selective oxidation of amines to imines is an attractive way to produce nitrile compounds, but it is limited by inefficient catalysts. Herein, we apply a oxyhydroxide layer formed on top of iron-doped layered nickel phosphorus trisulphides (Ni1-xFexPS3) to induce oxidation of benzylamine (BA). Structural and surface chemical characterizations during the electrocatalytic process combined with calculations reveal that Ni1-xFexPS3 undergoes surface reconstruction under alkaline conditions to form metal oxyhydroxide/phosphorus trichalcogenide (NiFeOOH/Ni1-xFexPS3) heterostructure. The heterointerface facilitates BA oxidation with a low onset potential of 1.39 V and Faradaic efficiency of 53% for benzonitrile synthesis. The NiFeOOH/Ni1-xFexPS3 heterostructure off ers optimum free energy for BA adsorption and benzonitrile desorption, resulting in promising benzonitrile synthesis. In article cey2.672, Wu et al.

Abstract Image

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Carbon Energy Multiple-

CiteScore

25.70

自引率

10.70%

发文量

116

审稿时长

4 weeks

期刊介绍： Carbon Energy is an international journal that focuses on cutting-edge energy technology involving carbon utilization and carbon emission control. It provides a platform for researchers to communicate their findings and critical opinions and aims to bring together the communities of advanced material and energy. The journal covers a broad range of energy technologies, including energy storage, photocatalysis, electrocatalysis, photoelectrocatalysis, and thermocatalysis. It covers all forms of energy, from conventional electric and thermal energy to those that catalyze chemical and biological transformations. Additionally, Carbon Energy promotes new technologies for controlling carbon emissions and the green production of carbon materials. The journal welcomes innovative interdisciplinary research with wide impact. It is indexed in various databases, including Advanced Technologies & Aerospace Collection/Database, Biological Science Collection/Database, CAS, DOAJ, Environmental Science Collection/Database, Web of Science and Technology Collection.