{"title":"Investigation of the non-equilibrium heat transfer and self-pressurization behavior of liquid hydrogen tanks","authors":"Hongyu Lv , Liang Chen , Zixin Zhang , Ze Zhang , Shuangtao Chen , Yu Hou","doi":"10.1016/j.ijhydene.2025.03.375","DOIUrl":null,"url":null,"abstract":"<div><div>Liquid hydrogen, due to its low boiling point and low latent heat of vaporization, is highly sensitive to external heat leakage, leading to thermodynamic phenomena such as heat and mass transfer, temperature rise, and self-pressurization within the tank. To accurately predict these behaviors in liquid hydrogen tanks, this study developed an evaporation-pressurization prediction model based on a modified three-zone model. The model is validated against classical experimental data, demonstrating high accuracy and applicability across a wide range of operating conditions, with an average maximum relative error of only 2.18 % for the six sets of predicted conditions. This study separates the influencing parameters into dimensionless form based on the gas state equation, compares the variation patterns of key parameters during the pressurization process, and explores the effects of different heat leakages, filling levels, and storage pressures on evaporation behavior. Finally, this study simulates the entire storage pressurization and depressurization process in liquid hydrogen tanks, precisely describing the evolution of various parameters during depressurization and examining the variations in the thermodynamic characteristics within the tank. This paper can enhance the comprehensive understanding and predictive capability of pressurization behavior in liquid hydrogen storage and transportation systems.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"122 ","pages":"Pages 125-138"},"PeriodicalIF":8.1000,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Hydrogen Energy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0360319925015265","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Liquid hydrogen, due to its low boiling point and low latent heat of vaporization, is highly sensitive to external heat leakage, leading to thermodynamic phenomena such as heat and mass transfer, temperature rise, and self-pressurization within the tank. To accurately predict these behaviors in liquid hydrogen tanks, this study developed an evaporation-pressurization prediction model based on a modified three-zone model. The model is validated against classical experimental data, demonstrating high accuracy and applicability across a wide range of operating conditions, with an average maximum relative error of only 2.18 % for the six sets of predicted conditions. This study separates the influencing parameters into dimensionless form based on the gas state equation, compares the variation patterns of key parameters during the pressurization process, and explores the effects of different heat leakages, filling levels, and storage pressures on evaporation behavior. Finally, this study simulates the entire storage pressurization and depressurization process in liquid hydrogen tanks, precisely describing the evolution of various parameters during depressurization and examining the variations in the thermodynamic characteristics within the tank. This paper can enhance the comprehensive understanding and predictive capability of pressurization behavior in liquid hydrogen storage and transportation systems.
期刊介绍:
The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc.
The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.