Concentration Dependent Modulation in Optoelectronic Traits of Self-Collated CsPbBr3 Perovskites

IF 13 2区材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Small Pub Date : 2025-04-01 DOI:10.1002/smll.202412614

Leepsa Mishra, Aradhana Panigrahi, Priyanka Dubey, Soumi Dutta, Himanshu Kumar, Manas Kumar Sarangi

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Abstract

Self-collation of perovskite nanocrystals into superstructures of larger length scales has been growing in research interest due to their dramatically enhanced performance in various nano-devices, modulating their optical and electrical traits. Herein, the unique concentration-dependent self-assembly of phenethylamine (PEA)-capped CsPbBr₃ (PCPB) perovskites spanning a size range of nano to micron level without structural phase alteration is infered. By optimizing various synthetic parameters like PEA amount, and solvents, the self-coalescence in PCPB crystal growth is controlled. Furthermore, the highest-concentrated PCPB (C5) has improved the charge transfer (CT) efficiency to 1,4-Napthoquinone (NPQ), corroborated with stronger binding between C5 and NPQ, compared to the lowest-concentrated PCPB (C1). Incorporating NPQ into such concentration-dependent PCPB enhances their local conductance unveiling the CT-induced current rise, while the detrimental insulating property of PEA molecules reduces the conductance in C5 compared to C1. These outcomes offer a foundation for tailoring the properties of self-assembled perovskites for optoelectronic devices and energy conversion technologies.

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来源期刊

Small 工程技术-材料科学：综合

CiteScore

17.70

自引率

3.80%

发文量

1830

审稿时长

2.1 months

期刊介绍： Small serves as an exceptional platform for both experimental and theoretical studies in fundamental and applied interdisciplinary research at the nano- and microscale. The journal offers a compelling mix of peer-reviewed Research Articles, Reviews, Perspectives, and Comments. With a remarkable 2022 Journal Impact Factor of 13.3 (Journal Citation Reports from Clarivate Analytics, 2023), Small remains among the top multidisciplinary journals, covering a wide range of topics at the interface of materials science, chemistry, physics, engineering, medicine, and biology. Small's readership includes biochemists, biologists, biomedical scientists, chemists, engineers, information technologists, materials scientists, physicists, and theoreticians alike.