Investigating the deformation behavior and microstructure evolution of Mg-3Zn-1Sn alloy with low activation energy of deformation during isothermal compression
{"title":"Investigating the deformation behavior and microstructure evolution of Mg-3Zn-1Sn alloy with low activation energy of deformation during isothermal compression","authors":"Shuai Yuan, Xiaohuan Pan, Xianhua Chen","doi":"10.1016/j.jallcom.2025.180093","DOIUrl":null,"url":null,"abstract":"Hot compression (HC) experiments were carried out on the homogenized Mg-3Zn-1Sn (ZT31, wt.%) alloy at various deformation parameters. The results indicated that both the increase in deformation temperature (T) and the decrease in strain rate (<span><span style=\"\"><math><mover accent=\"true\" is=\"true\"><mrow is=\"true\"><mi is=\"true\">ε</mi></mrow><mo is=\"true\">̇</mo></mover></math></span><span style=\"font-size: 90%; display: inline-block;\" tabindex=\"0\"><svg focusable=\"false\" height=\"1.971ex\" role=\"img\" style=\"vertical-align: -0.235ex;\" viewbox=\"0 -747.2 471.6 848.5\" width=\"1.095ex\" xmlns:xlink=\"http://www.w3.org/1999/xlink\"><g fill=\"currentColor\" stroke=\"currentColor\" stroke-width=\"0\" transform=\"matrix(1 0 0 -1 0 0)\"><g is=\"true\"><g is=\"true\"><g is=\"true\"><use xlink:href=\"#MJMATHI-3B5\"></use></g></g><g is=\"true\" transform=\"translate(161,-21)\"><use x=\"309\" xlink:href=\"#MJMAIN-307\" y=\"0\"></use></g></g></g></svg></span><script type=\"math/mml\"><math><mover accent=\"true\" is=\"true\"><mrow is=\"true\"><mi is=\"true\">ε</mi></mrow><mo is=\"true\">̇</mo></mover></math></script></span>) are responsible for the significant reduction in flow stress (<span><span style=\"\"><math><mi is=\"true\">σ</mi></math></span><span style=\"font-size: 90%; display: inline-block;\" tabindex=\"0\"></span><script type=\"math/mml\"><math><mi is=\"true\">σ</mi></math></script></span>). The calculated average activation energy of deformation during the considered conditions is 124<!-- --> <!-- -->kJ/mol, which is lower than many reported Mg alloys. Meanwhile, the ZT31 alloy has an instability criterion consistently greater than 0. Therefore, it exhibits outstanding hot deformation capability. The processing map shows that ZT31 alloy is safer to process above 300 °C, while the <span><span style=\"\"><math><mover accent=\"true\" is=\"true\"><mrow is=\"true\"><mi is=\"true\">ε</mi></mrow><mo is=\"true\">̇</mo></mover></math></span><span style=\"font-size: 90%; display: inline-block;\" tabindex=\"0\"></span><script type=\"math/mml\"><math><mover accent=\"true\" is=\"true\"><mrow is=\"true\"><mi is=\"true\">ε</mi></mrow><mo is=\"true\">̇</mo></mover></math></script></span> has a limited influence on the processability of ZT31 alloy. During the middle and late stages of deformation, the predominant deformation mechanisms of ZT31 alloy are basal slip and pyramidal <c+a> slip. The simultaneous activation of basal slip and pyramidal <c+a> slip puts the rotation of the c-axis in a dynamic balance, which ultimately manifests as the c-axis being approximately parallel to the compression direction (CD). The DRX mechanism of ZT31 alloy includes continuous DRX and discontinuous DRX.","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"12 1","pages":""},"PeriodicalIF":5.8000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Alloys and Compounds","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.jallcom.2025.180093","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Hot compression (HC) experiments were carried out on the homogenized Mg-3Zn-1Sn (ZT31, wt.%) alloy at various deformation parameters. The results indicated that both the increase in deformation temperature (T) and the decrease in strain rate () are responsible for the significant reduction in flow stress (). The calculated average activation energy of deformation during the considered conditions is 124 kJ/mol, which is lower than many reported Mg alloys. Meanwhile, the ZT31 alloy has an instability criterion consistently greater than 0. Therefore, it exhibits outstanding hot deformation capability. The processing map shows that ZT31 alloy is safer to process above 300 °C, while the has a limited influence on the processability of ZT31 alloy. During the middle and late stages of deformation, the predominant deformation mechanisms of ZT31 alloy are basal slip and pyramidal <c+a> slip. The simultaneous activation of basal slip and pyramidal <c+a> slip puts the rotation of the c-axis in a dynamic balance, which ultimately manifests as the c-axis being approximately parallel to the compression direction (CD). The DRX mechanism of ZT31 alloy includes continuous DRX and discontinuous DRX.
期刊介绍:
The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.