Gordon Binkhorst, Barbara Jones, Aelita Sargsyan, Alexander van Geen, Keith Wagner
{"title":"Potential Lead Exposure from Aluminum Cooking Pots in Lower and Middle-Income Countries","authors":"Gordon Binkhorst, Barbara Jones, Aelita Sargsyan, Alexander van Geen, Keith Wagner","doi":"10.1016/j.jhazmat.2025.138134","DOIUrl":null,"url":null,"abstract":"Food cooked in pots produced from recycled aluminum can contain impurities including lead, especially in lower and middle-income countries (LMICs) where quality control may be limited. Our study analyzed 113 mostly new aluminum pots from 25 LMICs for total lead with an XRF and lab-based leachable lead to mimic the release of lead while cooking. Total lead concentrations in the pots ranged from <5 ppm to almost 16,000 ppm, averaging 1,600 ppm, with the highest total lead concentrations in pots from Vietnam, Pakistan, Indonesia, and India. Leachable lead concentrations ranged from <1 to 2,900<!-- --> <!-- -->μg/L averaging 100<!-- --> <!-- -->μg/L after boiling 4% acetic acid for 2<!-- --> <!-- -->hours. Total and leachable lead concentrations were roughly proportional, with pots manufactured by casting leaching proportionally more lead compared to wrought pots manufactured from rolled aluminum. Optical microscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy of selected leached pots indicated a heterogeneous distribution of lead in the aluminum matrix and pitting of the aluminum along preferential pathways. Modelling using U.S. EPA’s All Ages Lead Model indicated that leachate concentrations >250<!-- --> <!-- -->μg/L, found in about one tenth of the pots tested, could result in blood lead levels that exceed the WHO’s intervention threshold of 5<!-- --> <!-- -->μg/dL in children and women of child-bearing age. This could be an overestimate, however, as laboratory leaching conditions were probably more aggressive than typical foods.","PeriodicalId":361,"journal":{"name":"Journal of Hazardous Materials","volume":"75 1","pages":""},"PeriodicalIF":12.2000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Hazardous Materials","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1016/j.jhazmat.2025.138134","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
引用次数: 0
Abstract
Food cooked in pots produced from recycled aluminum can contain impurities including lead, especially in lower and middle-income countries (LMICs) where quality control may be limited. Our study analyzed 113 mostly new aluminum pots from 25 LMICs for total lead with an XRF and lab-based leachable lead to mimic the release of lead while cooking. Total lead concentrations in the pots ranged from <5 ppm to almost 16,000 ppm, averaging 1,600 ppm, with the highest total lead concentrations in pots from Vietnam, Pakistan, Indonesia, and India. Leachable lead concentrations ranged from <1 to 2,900 μg/L averaging 100 μg/L after boiling 4% acetic acid for 2 hours. Total and leachable lead concentrations were roughly proportional, with pots manufactured by casting leaching proportionally more lead compared to wrought pots manufactured from rolled aluminum. Optical microscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy of selected leached pots indicated a heterogeneous distribution of lead in the aluminum matrix and pitting of the aluminum along preferential pathways. Modelling using U.S. EPA’s All Ages Lead Model indicated that leachate concentrations >250 μg/L, found in about one tenth of the pots tested, could result in blood lead levels that exceed the WHO’s intervention threshold of 5 μg/dL in children and women of child-bearing age. This could be an overestimate, however, as laboratory leaching conditions were probably more aggressive than typical foods.
期刊介绍:
The Journal of Hazardous Materials serves as a global platform for promoting cutting-edge research in the field of Environmental Science and Engineering. Our publication features a wide range of articles, including full-length research papers, review articles, and perspectives, with the aim of enhancing our understanding of the dangers and risks associated with various materials concerning public health and the environment. It is important to note that the term "environmental contaminants" refers specifically to substances that pose hazardous effects through contamination, while excluding those that do not have such impacts on the environment or human health. Moreover, we emphasize the distinction between wastes and hazardous materials in order to provide further clarity on the scope of the journal. We have a keen interest in exploring specific compounds and microbial agents that have adverse effects on the environment.