Hydrosilylation of Terminal Alkenes Catalyzed by a Scandium Metalloligand Supported Ni(0) Complex

IF 2.5 3区化学 Q2 CHEMISTRY, ORGANIC

European Journal of Organic Chemistry Pub Date : 2025-04-01 DOI:10.1002/ejoc.202500069

Lei Ma, Dongjing Hong, Peng Cui

引用次数: 0

Abstract

Hydrosilylation of terminal alkenes catalyzed by a scandium metalloligand supported Ni(0) complex were studied. The anti‐Markovnikov products were obtained in 62~89% yield, along with the alkanes and 1,1,2,2‐tetraphenyldisilane as minor products. The resting‐state complexes of hydrosilylation reactions were isolated and characterized by spectroscopic method and X‐ray diffraction studies, which represent rare‐example of Ni(0) silyl complexes supported by scandium ions via a Ni(0)→Sc(III) interaction. The catalytic cycle was proposed to be redox neutral with Ni(0) center, and was facilitated by metal‐ligand cooperation involving the Ni(0)‐Si bond.

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来源期刊

European Journal of Organic Chemistry 化学-有机化学

CiteScore

5.40

自引率

3.60%

发文量

752

审稿时长

1 months

期刊介绍： The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.