{"title":"Differences in microscopic properties of two major interfacial transition zones in interface between new and old concrete","authors":"Zhenghao Fu , Hongbing Zhu , Zhengfa Guo","doi":"10.1016/j.matlet.2025.138471","DOIUrl":null,"url":null,"abstract":"<div><div>At present, there are few microscopic explanations for the fact that excessive interfacial roughness is detrimental to interfacial bonding strength between new and old concrete. To enrich this research field, interfacial transition zone between old concrete’ aggregates and new concrete (ITZ-A) and interfacial transition zone between old concrete’ cement mortar and new concrete (ITZ-C) were as research subjects in this study. Their differences were investigated using scanning electron microscopy and energy dispersive spectroscopy. Comparative analysis revealed significant differences in three critical micro parameters: calcium-to-silicon content ratio (Ca/Si), the percentage of enriched region of CH and C-S-H, and microporosity characteristics. ITZ-C has 16.39 % less Ca/Si, 64.11 % less enriched regions of CH, 49.86 % more enriched regions of C-S-H, and 30.96 % less porosity than the ITZ-A. Moreover, ITZ-C porosity was dominated by sub-0.1 μm<sup>2</sup> micropores (45.26 % of total pore area), while ITZ-A exhibited predominant 1–5 μm<sup>2</sup> mesopores (39.08 % of total pore area). Based on the denseness and integrity of the matrix of the microstructure, the microscopic properties of ITZ-C were superior to those of ITZ-A.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"391 ","pages":"Article 138471"},"PeriodicalIF":2.7000,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Letters","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167577X25005002","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
At present, there are few microscopic explanations for the fact that excessive interfacial roughness is detrimental to interfacial bonding strength between new and old concrete. To enrich this research field, interfacial transition zone between old concrete’ aggregates and new concrete (ITZ-A) and interfacial transition zone between old concrete’ cement mortar and new concrete (ITZ-C) were as research subjects in this study. Their differences were investigated using scanning electron microscopy and energy dispersive spectroscopy. Comparative analysis revealed significant differences in three critical micro parameters: calcium-to-silicon content ratio (Ca/Si), the percentage of enriched region of CH and C-S-H, and microporosity characteristics. ITZ-C has 16.39 % less Ca/Si, 64.11 % less enriched regions of CH, 49.86 % more enriched regions of C-S-H, and 30.96 % less porosity than the ITZ-A. Moreover, ITZ-C porosity was dominated by sub-0.1 μm2 micropores (45.26 % of total pore area), while ITZ-A exhibited predominant 1–5 μm2 mesopores (39.08 % of total pore area). Based on the denseness and integrity of the matrix of the microstructure, the microscopic properties of ITZ-C were superior to those of ITZ-A.
期刊介绍:
Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials.
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